Chapter 8: Problem 49
Give three ions that are isoelectronic with neon. Place these ions in order of increasing size.
Chapter 8: Problem 49
Give three ions that are isoelectronic with neon. Place these ions in order of increasing size.
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Get started for freeA compound, \(\mathrm{XF}_{5}\), is \(42.81 \%\) fluorine by mass. Identify the element \(X\). What is the molecular structure of \(\mathrm{XF}_{5}\) ?
The structure of \(\mathrm{TeF}_{5}^{-}\) is Draw a complete Lewis structure for \(\mathrm{TeF}_{5}^{-}\), and explain the distortion from the ideal square pyramidal structure. (See Exercise 106.)
Identify the five compounds of \(\mathrm{H}, \mathrm{N}\), and \(\mathrm{O}\) described below. For each compound, write a Lewis structure that is consistent with the information given. a. All the compounds are electrolytes, although not all of them are strong electrolytes. Compounds \(\mathrm{C}\) and \(\mathrm{D}\) are ionic and compound \(\mathrm{B}\) is covalent. b. Nitrogen occurs in its highest possible oxidation state in compounds \(\mathrm{A}\) and \(\mathrm{C}\); nitrogen occurs in its lowest possible oxidation state in compounds \(\mathrm{C}, \mathrm{D}\), and \(\mathrm{E}\). The formal charge on both nitrogens in compound \(\mathrm{C}\) is \(+1\); the formal charge on the only nitrogen in compound \(\mathrm{B}\) is \(0 .\) c. Compounds A and E exist in solution. Both solutions give off gases. Commercially available concentrated solutions of compound \(\mathrm{A}\) are normally \(16 M .\) The commercial, concentrated solution of compound \(\mathrm{E}\) is \(15 M\). d. Commercial solutions of compound \(\mathrm{E}\) are labeled with a misnomer that implies that a binary, gaseous compound of nitrogen and hydrogen has reacted with water to produce ammonium ions and hydroxide ions. Actually, this reaction occurs to only a slight extent. e. Compound \(\mathrm{D}\) is \(43.7 \% \mathrm{~N}\) and \(50.0 \% \mathrm{O}\) by mass. If compound D were a gas at STP, it would have a density of \(2.86 \mathrm{~g} / \mathrm{L}\). f. A formula unit of compound \(\mathrm{C}\) has one more oxygen than a formula unit of compound D. Compounds \(\mathrm{C}\) and \(\mathrm{A}\) have one ion in common when compound \(\mathrm{A}\) is acting as a strong electrolyte. g. Solutions of compound \(\mathrm{C}\) are weakly acidic; solutions of compound \(\mathrm{A}\) are strongly acidic; solutions of compounds \(\mathrm{B}\) and \(\mathrm{E}\) are basic. The titration of \(0.726 \mathrm{~g}\) compound \(\mathrm{B}\) requires \(21.98 \mathrm{~mL}\) of \(1.000 M \mathrm{HCl}\) for complete neutralization.
Write Lewis structures that obey the octet rule for the following species. Assign the formal charge for each central atom. a. \(\mathrm{POCl}_{3}\) e. \(\mathrm{SO}_{2} \mathrm{Cl}_{2}\) b. \(\mathrm{SO}_{4}^{2-}\) f. \(\mathrm{XeO}_{4}\) c. \(\mathrm{ClO}_{4}^{-}\) g. \(\mathrm{ClO}_{3}^{-}\) d. \(\mathrm{PO}_{4}^{3-}\) h. \(\mathrm{NO}_{4}^{3-}\)
The alkali metal ions are very important for the proper functioning of biologic systems, such as nerves and muscles, and \(\mathrm{Na}^{+}\) and \(\mathrm{K}^{+}\) ions are present in all body cells and fluids. In human blood plasma, the concentrations are $$ \left[\mathrm{Na}^{+}\right] \approx 0.15 M \text { and }\left[\mathrm{K}^{+}\right] \approx 0.005 M $$ For the fluids inside the cells, the concentrations are reversed: $$ \left[\mathrm{Na}^{+}\right] \approx 0.005 M \text { and }\left[\mathrm{K}^{+}\right] \approx 0.16 M $$ Since the concentrations are so different inside and outside the cells, an elaborate mechanism is needed to transport \(\mathrm{Na}^{+}\) and \(\mathrm{K}^{+}\) ions through the cell membranes. What are the ground-state electron configurations for \(\mathrm{Na}^{+}\) and \(\mathrm{K}^{+}\) ? Which ion is smaller in size? Counterions also must be present in blood plasma and inside intracellular fluid. Assume the counterion present to balance the positive charge of \(\mathrm{Na}^{+}\) and \(\mathrm{K}^{+}\) is \(\mathrm{Cl}^{-}\). What is the ground-state electron configuration for \(\mathrm{Cl}^{-}\) ? Rank these three ions in order of increasing size.
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