The wave function for the \(2 p_{z}\) orbital in the hydrogen atom is
$$
\psi_{2 p_{z}}=\frac{1}{4 \sqrt{2 \pi}}\left(\frac{Z}{a_{0}}\right)^{3 / 2}
\sigma \mathrm{e}^{-\sigma / 2} \cos \theta
$$
where \(a_{0}\) is the value for the radius of the first Bohr orbit in meters
\(\left(5.29 \times 10^{-11}\right), \sigma\) is \(Z\left(r / a_{0}\right), r\) is
the value for the distance from the nucleus in meters, and \(\theta\) is an
angle. Calculate the value of \(\psi_{2 p_{p}}^{2}\) at \(r=a_{0}\) for
\(\theta=0^{\circ}\left(z\right.\) axis) and for \(\theta=90^{\circ}(x y\) plane).