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The Bohr model only works for one electron species. Why do we discuss it in this text (what's good about it)?

Short Answer

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The Bohr model is discussed in physics and chemistry texts due to its simplicity, ease of calculation for hydrogen-like atoms, foundational role in quantum mechanics, its ability to explain spectral lines in the hydrogen atom, and its educational value as an excellent starting point for understanding atomic structure. Even though the model has limitations and has been surpassed by more advanced models like the Schrödinger model, it helps students build a strong foundation for further learning in atomic and quantum physics.

Step by step solution

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1. Introduction to the Bohr Model

The Bohr model, proposed by Niels Bohr in 1913, is an early model of atomic structure and only works for one-electron species like hydrogen and hydrogen-like ions (such as He+ and Li²⁺). The model successfully explains the hydrogen atom's energy levels, electron orbits, and quantized energy emissions.
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2. Simplicity and Calculation

One of the key advantages of the Bohr model is its simplicity. It offers a straightforward way to calculate the energy levels of hydrogen-like atoms. Using the Bohr model, we can easily determine the electron's energy in each orbit around the nucleus using the formula \(E_n = -\frac{13.6 eV}{n^2}\), where n is the principal quantum number (integer n≥1).
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3. Foundation for Quantum Mechanics

Even though the Bohr model has limitations, it sets the stage for the development of quantum mechanics. The idea of quantized energy levels and the wave-particle duality introduced by the model are fundamental concepts in quantum theory. These concepts were further elaborated and refined by scientists like Erwin Schrödinger, Werner Heisenberg, and Max Born, who contributed to the development of the modern quantum mechanics theory.
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4. Spectral Lines of Hydrogen Atom

The Bohr model accurately predicts the hydrogen atoms' spectral lines, also known as the hydrogen emission spectrum. The model explains the observed spectral lines by the electrons absorbing or emitting photons. As the electrons transition between energy levels (orbits), they absorb or emit energy corresponding to the difference in energy levels. This energy difference is observed as discrete lines in the emission spectrum.
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5. Educational Value

Despite its limitations, the Bohr model is widely discussed in educational settings because it serves as an excellent starting point for introducing the concept of atomic structure. The model's simplicity and visualization of electron orbits help students easily grasp the essentials of atomic theory. In conclusion, even though the Bohr model has its limitations, it is discussed in physics and chemistry texts because of its simplicity, ease of calculation, foundational role in quantum mechanics, the explanation of spectral lines in the hydrogen atom, and its educational value. While more advanced models like the Schrödinger model have surpassed the Bohr model, understanding the Bohr model helps students build a strong foundation for further learning in atomic and quantum physics.

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Most popular questions from this chapter

As the weapons officer aboard the Starship Chemistry, it is your duty to configure a photon torpedo to remove an electron from the outer hull of an enemy vessel. You know that the work function (the binding energy of the electron) of the hull of the enemy ship is \(7.52 \times 10^{-19} \mathrm{~J}\). a. What wavelength does your photon torpedo need to be to eject an electron? b. You find an extra photon torpedo with a wavelength of 259 \(\mathrm{nm}\) and fire it at the enemy vessel. Does this photon torpedo do any damage to the ship (does it eject an electron)? c. If the hull of the enemy vessel is made of the element with an electron configuration of \([\mathrm{Ar}] 4 s^{1} 3 d^{10}\), what metal is this?

What is the physical significance of the value of \(\psi^{2}\) at a particular point in an atomic orbital?

Which of the following sets of quantum numbers are not allowed in the hydrogen atom? For the sets of quantum numbers that are incorrect, state what is wrong in each set. a. \(n=3, \ell=2, m_{\ell}=2\) b. \(n=4, \ell=3, m_{\ell}=4\) c. \(n=0, \ell=0, m_{\ell}=0\) d. \(n=2, \ell=-1, m_{\ell}=1\)

Consider an electron for a hydrogen atom in an excited state. The maximum wavelength of electromagnetic radiation that can completely remove (ionize) the electron from the \(\mathrm{H}\) atom is \(1460 \mathrm{~nm} .\) What is the initial excited state for the electron \((n=?) ?\)

In each of the following sets, which atom or ion has the smallest radius? a. \(\mathrm{H}, \mathrm{He}\) b. \(\mathrm{Cl}\), In, Se c. element 120 , element 119 , element 116 d. \(\mathrm{Nb}, \mathrm{Zn}, \mathrm{Si}\) e. \(\mathrm{Na}^{-}, \mathrm{Na}, \mathrm{Na}^{+}\)

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