Chapter 7: Problem 108
Rank the elements \(\mathrm{Be}, \mathrm{B}, \mathrm{C}, \mathrm{N}\), and \(\mathrm{O}\) in order of increasing first ionization energy. Explain your reasoning.
Chapter 7: Problem 108
Rank the elements \(\mathrm{Be}, \mathrm{B}, \mathrm{C}, \mathrm{N}\), and \(\mathrm{O}\) in order of increasing first ionization energy. Explain your reasoning.
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Get started for freeConsider the following ionization energies for aluminum: $$ \begin{aligned} \mathrm{Al}(g) \longrightarrow \mathrm{Al}^{+}(g)+\mathrm{e}^{-} & I_{1}=580 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{Al}^{+}(g) \longrightarrow \mathrm{Al}^{2+}(g)+\mathrm{e}^{-} & I_{2}=1815 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ $$ \begin{array}{ll} \mathrm{Al}^{2+}(g) \longrightarrow \mathrm{Al}^{3+}(g)+\mathrm{e}^{-} & I_{3}=2740 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{Al}^{3+}(g) \longrightarrow \mathrm{Al}^{4+}(g)+\mathrm{e}^{-} & I_{4}=11,600 \mathrm{~kJ} / \mathrm{mol} \end{array} $$ a. Account for the trend in the values of the ionization energies. b. Explain the large increase between \(I_{3}\) and \(I_{4}\). c. Which one of the four ions has the greatest electron affinity? Explain. d. List the four aluminum ions given in order of increasing size, and explain your ordering. (Hint: Remember that most of the size of an atom or ion is due to its electrons.)
Give a possible set of values of the four quantum numbers for all the electrons in a boron atom and a nitrogen atom if each is in the ground state.
Carbon absorbs energy at a wavelength of \(150 . \mathrm{nm}\). The total amount of energy emitted by a carbon sample is \(1.98 \times 10^{5} \mathrm{~J}\). Calculate the number of carbon atoms present in the sample, assuming that each atom emits one photon.
Are the following statements true for the hydrogen atom only, true for all atoms, or not true for any atoms? a. The principal quantum number completely determines the energy of a given electron. b. The angular momentum quantum number, \(\ell\), determines the shapes of the atomic orbitals. c. The magnetic quantum number, \(m_{\ell}\), determines the direction that the atomic orbitals point in space.
Which has the more negative electron affinity, the oxygen atom or the \(\mathrm{O}^{-}\) ion? Explain your answer.
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