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A \(5.00-\mathrm{g}\) sample of aluminum pellets (specific heat capacity \(=\) \(0.89 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) ) and a \(10.00-\mathrm{g}\) sample of iron pellets (specific heat capacity \(=0.45 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) ) are heated to \(100.0^{\circ} \mathrm{C}\). The mixture of hot iron and aluminum is then dropped into \(97.3 \mathrm{~g}\) water at \(22.0^{\circ} \mathrm{C}\). Calculate the final temperature of the metal and water mixture, assuming no heat loss to the surroundings.

Short Answer

Expert verified
The final temperature of the metal and water mixture is approximately \(26.0^{\circ} \mathrm{C}\).

Step by step solution

01

1. Write down the energy conservation equation

The heat energy lost by the hot aluminum and iron pellets is equal to the heat gained by the water. We can write the energy conservation equation as follows: $$Q_{lost} = Q_{gained}$$
02

2. Calculate the heat energy lost by aluminum pellets

To calculate the heat energy lost by the aluminum pellets, we'll use the formula: $$Q_{aluminum} = m_{aluminum} \times c_{aluminum} \times (\Delta T)_{aluminum}$$ where \(Q_{aluminum}\) is the heat energy lost by the aluminum pellets, \(m_{aluminum}\) is the mass of the aluminum pellets, \(c_{aluminum}\) is the specific heat capacity of aluminum, and \((\Delta T)_{aluminum}\) is the change in temperature of the aluminum pellets. We have: \(m_{aluminum} = 5.00 \,\text{g}\) \(c_{aluminum} = 0.89 \,\mathrm{J} /{ }(^{\circ} \mathrm{C}) \cdot \mathrm{g}\) Initial temperature of the aluminum pellets, \(T_{initial}^{aluminum} = 100.0^{\circ} \mathrm{C}\) Final temperature of the aluminum pellets, \(T_{final}^{aluminum} = T_{final}\) (which we need to find) So, the temperature change is given by: \((\Delta T)_{aluminum} = T_{final} - T_{initial}^{aluminum}\)
03

3. Calculate the heat energy lost by iron pellets

To calculate the heat energy lost by the iron pellets, we'll use the formula: $$Q_{iron} = m_{iron} \times c_{iron} \times (\Delta T)_{iron}$$ where \(Q_{iron}\) is the heat energy lost by the iron pellets, \(m_{iron}\) is the mass of the iron pellets, \(c_{iron}\) is the specific heat capacity of iron, and \((\Delta T)_{iron}\) is the change in temperature of the iron pellets. We have: \(m_{iron} = 10.00 \,\mathrm{g}\) \(c_{iron} = 0.45 \,\mathrm{J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) Initial temperature of the iron pellets, \(T_{initial}^{iron} = 100.0^{\circ} \mathrm{C}\) Final temperature of the iron pellets, \(T_{final}^{iron} = T_{final}\) (which we need to find) So, the temperature change is given by: \((\Delta T)_{iron} = T_{final} - T_{initial}^{iron}\)
04

4. Calculate the heat energy gained by water

To calculate the heat energy gained by water, we'll use the formula: $$Q_{water} = m_{water} \times c_{water} \times (\Delta T)_{water}$$ where \(Q_{water}\) is the heat energy gained by water, \(m_{water}\) is the mass of the water, \(c_{water}\) is the specific heat capacity of water, and \((\Delta T)_{water}\) is the change in temperature of water. We have: \(m_{water} = 97.3 \,\mathrm{g}\) \(c_{water} = 4.18 \,\mathrm{J} / { }^{\circ} \mathrm{C} \cdot \mathrm{g}\) (approx) Initial temperature of water, \(T_{initial}^{water} = 22.0^{\circ} \mathrm{C}\) Final temperature of water, \(T_{final}^{water} = T_{final}\) (which we need to find) So, the temperature change is given by: \((\Delta T)_{water} = T_{final} - T_{initial}^{water}\)
05

5. Write down the energy conservation equation with found expressions

Putting the expressions from steps 2, 3, and 4, we rewrite the energy conservation equation: $$m_{aluminum} \times c_{aluminum} \times (T_{final} - T_{initial}^{aluminum}) + m_{iron} \times c_{iron} \times (T_{final} - T_{initial}^{iron}) = m_{water} \times c_{water} \times (T_{final} - T_{initial}^{water})$$
06

6. Solve for the final temperature

Now we need to solve the equation in step 5 for \(T_{final}\): $$5.00 \times 0.89 \times (T_{final} - 100.0) + 10.00 \times 0.45 \times (T_{final} - 100.0) = 97.3 \times 4.18 \times (T_{final} - 22.0)$$ On solving for \(T_{final}\), we get: $$T_{final} \approx 26.0^{\circ} \mathrm{C}$$ Therefore, the final temperature of the metal and water mixture is approximately \(26.0^{\circ} \mathrm{C}\).

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Most popular questions from this chapter

The Ostwald process for the commercial production of nitric acid from ammonia and oxygen involves the following steps: $$ \begin{aligned} 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) & \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \\ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}_{2}(g) \\ 3 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) & \longrightarrow 2 \mathrm{HNO}_{3}(a q)+\mathrm{NO}(g) \end{aligned} $$ a. Use the values of \(\Delta H_{\mathrm{f}}^{\circ}\) in Appendix 4 to calculate the value of \(\Delta H^{\circ}\) for each of the preceding reactions. b. Write the overall equation for the production of nitric acid by the Ostwald process by combining the preceding equations. (Water is also a product.) Is the overall reaction exothermic or endothermic?

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Consider \(5.5 \mathrm{~L}\) of a gas at a pressure of \(3.0 \mathrm{~atm}\) in a cylinder with a movable piston. The external pressure is changed so that the volume changes to \(10.5 \mathrm{~L}\). a. Calculate the work done, and indicate the correct sign. b. Use the preceding data but consider the process to occur in two steps. At the end of the first step, the volume is \(7.0 \mathrm{~L}\). The second step results in a final volume of \(10.5\) L. Calculate the work done, and indicate the correct sign. c. Calculate the work done if after the first step the volume is \(8.0 \mathrm{~L}\) and the second step leads to a volume of \(10.5 \mathrm{~L}\). Does the work differ from that in part b? Explain.

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