Chapter 6: Problem 27
A gas absorbs \(45 \mathrm{~kJ}\) of heat and does \(29 \mathrm{~kJ}\) of work. Calculate \(\Delta E\).
Chapter 6: Problem 27
A gas absorbs \(45 \mathrm{~kJ}\) of heat and does \(29 \mathrm{~kJ}\) of work. Calculate \(\Delta E\).
All the tools & learning materials you need for study success - in one app.
Get started for freeOn Easter Sunday, April 3, 1983 , nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: \(2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\) a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times 10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing \(70.0 \% \mathrm{HNO}_{3}\) by mass with a density of \(1.42 \mathrm{~g} / \mathrm{cm}^{3}\). What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? \(\left(\Delta H_{\mathrm{f}}^{\circ}\right.\) for \(\mathrm{NaNO}_{3}(a q)=-467 \mathrm{~kJ} / \mathrm{mol}\) ) b. According to The Denver Post for April 4, 1983 , authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ}\), what was their major concern?
Explain the advantages and disadvantages of hydrogen as an alternative fuel.
The enthalpy of combustion of \(\mathrm{CH}_{4}(\mathrm{~g})\) when \(\mathrm{H}_{2} \mathrm{O}(l)\) is formed is \(-891 \mathrm{~kJ} / \mathrm{mol}\) and the enthalpy of combustion of \(\mathrm{CH}_{4}(\mathrm{~g})\) when \(\mathrm{H}_{2} \mathrm{O}(\mathrm{g})\) is formed is \(-803 \mathrm{~kJ} / \mathrm{mol} .\) Use these data and Hess's law to determine the enthalpy of vaporization for water.
The standard enthalpy of formation of \(\mathrm{H}_{2} \mathrm{O}(l)\) at \(298 \mathrm{~K}\) is \(-285.8\) \(\mathrm{kJ} / \mathrm{mol} .\) Calculate the change in internal energy for the following process at \(298 \mathrm{~K}\) and 1 atm: $$ \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \quad \Delta E^{\circ}=? $$ (Hint: Using the ideal gas equation, derive an expression for work in terms of \(n, R\), and \(T\).)
Assuming gasoline is pure \(\mathrm{C}_{8} \mathrm{H}_{1 \mathrm{~s}}(l)\), predict the signs of \(q\) and \(w\) for the process of combusting gasoline into \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) .\)
What do you think about this solution?
We value your feedback to improve our textbook solutions.