Chapter 5: Problem 11
If you release a helium balloon, it soars upward and eventually pops. Explain this behavior.
Chapter 5: Problem 11
If you release a helium balloon, it soars upward and eventually pops. Explain this behavior.
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Get started for freeIdeal gas particles are assumed to be volumeless and to neither attract nor repel each other. Why are these assumptions crucial to the validity of Dalton's law of partial pressures?
Do all the molecules in a 1 -mol sample of \(\mathrm{CH}_{4}(g)\) have the same kinetic energy at \(273 \mathrm{~K}\) ? Do all molecules in a \(1-\mathrm{mol}\) sample of \(\mathrm{N}_{2}(g)\) have the same velocity at \(546 \mathrm{~K}\) ? Explain.
In the presence of nitric acid, \(\mathrm{UO}^{2+}\) undergoes a redox process. It is converted to \(\mathrm{UO}_{2}{ }^{2+}\) and nitric oxide (NO) gas is produced according to the following unbalanced equation: \(\mathrm{H}^{+}(a q)+\mathrm{NO}_{3}^{-}(a q)+\mathrm{UO}^{2+}(a q)\) \(\mathrm{NO}(g)+\mathrm{UO}_{2}^{2+}(a q)+\mathrm{H}_{2} \mathrm{O}(l)\) If \(2.55 \times 10^{2} \mathrm{~mL} \mathrm{NO}(g)\) is isolated at \(29^{\circ} \mathrm{C}\) and \(1.5 \mathrm{~atm}\), what amount (moles) of \(\mathrm{UO}^{2+}\) was used in the reaction? (Hint: Balance the reaction by the oxidation states method.)
A 20.0-L stainless steel container at \(25^{\circ} \mathrm{C}\) was charged with \(2.00\) atm of hydrogen gas and \(3.00 \mathrm{~atm}\) of oxygen gas. A spark ignited the mixture, producing water. What is the pressure in the tank at \(25^{\circ} \mathrm{C}\) ? If the same experiment were performed, but the temperature was \(125^{\circ} \mathrm{C}\) instead of \(25^{\circ} \mathrm{C}\), what would be the pressure in the tank?
In 1897 the Swedish explorer Andreé tried to reach the North Pole in a balloon. The balloon was filled with hydrogen gas. The hydrogen gas was prepared from iron splints and diluted sulfuric acid. The reaction is $$ \mathrm{Fe}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{FeSO}_{4}(a q)+\mathrm{H}_{2}(g) $$ The volume of the balloon was \(4800 \mathrm{~m}^{3}\) and the loss of hydrogen gas during filling was estimated at \(20 . \%\). What mass of iron splints and \(98 \%\) (by mass) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) were needed to ensure the complete filling of the balloon? Assume a temperature of \(0^{\circ} \mathrm{C}, \mathrm{a}\) pressure of \(1.0\) atm during filling, and \(100 \%\) yield.
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