Chapter 4: Problem 33
What mass of \(\mathrm{NaOH}\) is contained in \(250.0 \mathrm{~mL}\) of a \(0.400 \mathrm{M}\) sodium hydroxide solution?
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Write net ionic equations for the reaction, if any, that occurs when aqueous solutions of the following are mixed. a. chromium(III) chloride and sodium hydroxide b. silver nitrate and ammonium carbonate c. copper(II) sulfate and mercury(I) nitrate d. strontium nitrate and potassium iodide
You are given a \(1.50-\mathrm{g}\) mixture of sodium nitrate and sodium chloride. You dissolve this mixture into \(100 \mathrm{~mL}\) of water and then add an excess of \(0.500 \mathrm{M}\) silver nitrate solution. You produce a white solid, which you then collect, dry, and measure. The white solid has a mass of \(0.641 \mathrm{~g}\). a. If you had an extremely magnified view of the solution (to the atomic- molecular level), list the species you would see (include charges, if any). b. Write the balanced net ionic equation for the reaction that produces the solid. Include phases and charges. c. Calculate the percent sodium chloride in the original unknown mixture.
Carminic acid, a naturally occurring red pigment extracted from the cochineal insect, contains only carbon, hydrogen, and oxygen. It was commonly used as a dye in the first half of the nineteenth century. It is \(53.66 \% \mathrm{C}\) and \(4.09 \% \mathrm{H}\) by mass. A titration required \(18.02 \mathrm{~mL}\) of \(0.0406 \mathrm{M} \mathrm{NaOH}\) to neutralize \(0.3602 \mathrm{~g}\) carminic acid. Assuming that there is only one acidic hydrogen per molecule, what is the molecular formula of carminic acid?
On the basis of the general solubility rules given in Table 4.1, predict which of the following substances are likely to be soluble in water. a. aluminum nitrate b. magnesium chloride c. rubidium sulfate d. nickel(II) hydroxide e. lead(II) sulfide f. magnesium hydroxide g. iron(III) phosphate
Douglasite is a mineral with the formula \(2 \mathrm{KCl} \cdot \mathrm{FeCl}_{2} \cdot 2 \mathrm{H}_{2} \mathrm{O}\). Calculate the mass percent of douglasite in a \(455.0-\mathrm{mg}\) sample if it took \(37.20 \mathrm{~mL}\) of a \(0.1000 \mathrm{M} \mathrm{AgNO}_{3}\) solution to precipitate all the \(\mathrm{Cl}^{-}\) as \(\mathrm{AgCl}\). Assume the douglasite is the only source of chloride ion.
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