Chapter 22: Problem 56
Draw the structural formula for each of the following. a. formaldehyde (methanal) b. 4 -heptanone c. 3 -chlorobutanal d. 5,5 -dimethyl-2-hexanone
Chapter 22: Problem 56
Draw the structural formula for each of the following. a. formaldehyde (methanal) b. 4 -heptanone c. 3 -chlorobutanal d. 5,5 -dimethyl-2-hexanone
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Get started for freeIn the presence of light, chlorine can substitute for one (or more) of the hydrogens in an alkane. For the following reactions, draw the possible monochlorination products. a. 2,2 -dimethylpropane \(+\mathrm{Cl}_{2} \stackrel{\mathrm{hv}}{\longrightarrow}\) b. 1,3 -dimethylcyclobutane \(+\mathrm{Cl}_{2} \stackrel{\text { hv }}{\longrightarrow}\) c. 2,3 -dimethylbutane \(+\mathrm{Cl}_{2} \stackrel{\mathrm{hv}^{-}}{\longrightarrow}\)
Oxidation of an aldehyde yields a carboxylic acid: Draw the structures for the products of the following oxidation reactions. a. propanal \(\stackrel{[\mathrm{ax}]}{\longrightarrow}\) b. 2,3 -dimethylpentanal \(\stackrel{[\mathrm{ax}]}{\longrightarrow}\) c. 3 -ethylbenzaldehyde \(\stackrel{[\mathrm{ax}]}{\longrightarrow}\)
Helicenes are extended fused polyaromatic hydrocarbons that have a helical or screw-shaped structure. a. A \(0.1450-\mathrm{g}\) sample of solid helicene is combusted in air to give \(0.5063 \mathrm{~g} \mathrm{CO}_{2} .\) What is the empirical formula of this helicene? b. If a \(0.0938-\mathrm{g}\) sample of this helicene is dissolved in \(12.5 \mathrm{~g}\) of solvent to give a \(0.0175 \mathrm{~m}\) solution, what is the molecular formula of this helicene? c. What is the balanced reaction for the combustion of this helicene?
Explain why methyl alcohol is soluble in water in all proportions, while stearyl alcohol \(\left[\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{OH}\right]\) is a waxy solid that is not soluble in water.
Diborane, \(\mathrm{B}_{2} \mathrm{H}_{6}\), is a highly unstable compound that reacts explosively with oxygen. Ethane, \(\mathrm{C}_{2} \mathrm{H}_{6}\), combines with oxygen only at elevated temperatures. Explain the differences in these two compounds.
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