Chapter 21: Problem 73
What causes high-altitude sickness, and what is high-altitude acclimatization?
Chapter 21: Problem 73
What causes high-altitude sickness, and what is high-altitude acclimatization?
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Get started for freeIn the production of printed circuit boards for the electronics industry, a \(0.60-\mathrm{mm}\) layer of copper is laminated onto an insulating plastic board. Next, a circuit pattern made of a chemically resistant polymer is printed on the board. The unwanted copper is removed by chemical etching, and the protective polymer is finally removed by solvents. One etching reaction is \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}(a q)+4 \mathrm{NH}_{3}(a q)+\mathrm{Cu}(s)\) \(\longrightarrow 2\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}(a q)\) a. Is this reaction an oxidation-reduction process? Explain. b. \(A\) plant needs to manufacture 10,000 printed circuit boards, each \(8.0 \times 16.0 \mathrm{~cm}\) in area. An average of \(80 . \%\) of the copper is removed from each board (density of copper \(=8.96\) \(\mathrm{g} / \mathrm{cm}^{3}\) ). What masses of \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\) and \(\mathrm{NH}_{3}\) are needed to do this? Assume \(100 \%\) yield.
A transition metal compound contains a cobalt ion, chloride ions, and water molecules. The \(\mathrm{H}_{2} \mathrm{O}\) molecules are the ligands in the complex ion and the \(\mathrm{Cl}^{-}\) ions are the counterions. \(\mathrm{A}\) \(0.256-\mathrm{g}\) sample of the compound was dissolved in water, and excess silver nitrate was added. The silver chloride was filtered, dried, and weighed, and it had a mass of \(0.308 \mathrm{~g}\). A second sample of \(0.416 \mathrm{~g}\) of the compound was dissolved in water, and an excess of sodium hydroxide was added. The hydroxide salt was filtered and heated in a flame, forming cobalt(III) oxide. The mass of cobalt(III) oxide formed was \(0.145 \mathrm{~g}\). What is the oxidation state of cobalt in the complex ion and what is the formula of the compound?
Sketch and explain the most likely pattem for the crystal field diagram for the complex ion trans-diamminetetracyanonickelate(II), where \(\mathrm{CN}^{-}\) produces a much stronger crystal field than \(\mathrm{NH}_{3}\). Explain completely and label the \(d\) orbitals in your diagram. Assume the \(\mathrm{NH}_{3}\) ligands lie on the \(z\) axis.
Figure \(21.17\) shows that the cis isomer of \(\mathrm{Co}(\mathrm{en})_{2} \mathrm{Cl}_{2}^{+}\) is optically active while the trans isomer is not optically active. Is the same true for \(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}^{+} ?\) Explain.
How many unpaired electrons are in the following complex ions? a. \(\mathrm{Ru}\left(\mathrm{NH}_{3}\right)_{6}^{2+}\) (low-spin case) b. \(\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) c. \(\mathrm{V}(\mathrm{en})_{3}{ }^{3+}\)
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