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Write electron configurations for each of the following. a. \(\mathrm{Cr}, \mathrm{Cr}^{2+}, \mathrm{Cr}^{3+}\) b. \(\mathrm{Cu}, \mathrm{Cu}^{+}, \mathrm{Cu}^{2+}\) c. \(\mathrm{V}, \mathrm{V}^{2+}, \mathrm{V}^{3+}\)

Short Answer

Expert verified
a. Cr: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{1}3d^{5}\), Cr²⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{4}\), Cr³⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{3}\) b. Cu: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{1}3d^{10}\), Cu⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{10}\), Cu²⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{9}\) c. V: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{2}3d^{3}\), V²⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{2}\), V³⁺: \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{1}\)

Step by step solution

01

Determine the atomic number of the element

The atomic number of Chromium (Cr) is 24.
02

Write the electron configuration for Cr

Using the periodic table and applying the rules, we find the electron configuration of Chromium to be: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{1}3d^{5}\]
03

Write the electron configuration for Cr²⁺

For the Cr²⁺ ion, we need to remove two electrons. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{4}\]
04

Write the electron configuration for Cr³⁺

For the Cr³⁺ ion, we need to remove three electrons. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{3}\] b. Cu, Cu⁺, Cu²⁺
05

Determine the atomic number of the element

The atomic number of Copper (Cu) is 29.
06

Write the electron configuration for Cu

Using the periodic table and applying the rules, we find the electron configuration of Copper to be: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{1}3d^{10}\]
07

Write the electron configuration for Cu⁺

For the Cu⁺ ion, we need to remove one electron. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{10}\]
08

Write the electron configuration for Cu²⁺

For the Cu²⁺ ion, we need to remove two electrons. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{9}\] c. V, V²⁺, V³⁺
09

Determine the atomic number of the element

The atomic number of Vanadium (V) is 23.
10

Write the electron configuration for V

Using the periodic table and applying the rules, we find the electron configuration of Vanadium to be: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{2}3d^{3}\]
11

Write the electron configuration for V²⁺

For the V²⁺ ion, we need to remove two electrons. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{2}\]
12

Write the electron configuration for V³⁺

For the V³⁺ ion, we need to remove three electrons. The electron configuration becomes: \[1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{1}\]

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Most popular questions from this chapter

Draw geometrical isomers of each of the following complex ions. a. \(\left[\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\right]^{-}\) c. \(\left[\operatorname{Ir}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\) b. \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{I}_{2}\right]^{2+}\) d. \(\left[\mathrm{Cr}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{2} \mathrm{I}_{2}\right]^{+}\)

Draw all the geometrical isomers of \(\left[\mathrm{Cr}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{2} \mathrm{BrCl}\right]^{+} .\) Which of these isomers also have an optical isomer? Draw the various isomers.

There are three salts that contain complex ions of chromium and have the molecular formula \(\mathrm{CrCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\). Treating \(0.27 \mathrm{~g}\) of the first salt with a strong dehydrating agent resulted in a mass loss of \(0.036 \mathrm{~g}\). Treating \(270 \mathrm{mg}\) of the second salt with the same dehydrating agent resulted in a mass loss of \(18 \mathrm{mg}\). The third salt did not lose any mass when treated with the same dehydrating agent. Addition of excess aqueous silver nitrate to \(100.0-\mathrm{mL}\) portions of \(0.100 M\) solutions of each salt resulted in the formation of different masses of silver chloride; one solution yielded 1430 \(\mathrm{mg} \mathrm{AgCl} ;\) another, \(2870 \mathrm{mg} \mathrm{AgCl}\); the third, \(4300 \mathrm{mg} \mathrm{AgCl}\). Two of the salts are green and one is violet. Suggest probable structural formulas for these salts, defending your answer on the basis of the preceding observations. State which salt is most likely to be violet. Would a study of the magnetic properties of the salts be helpful in determining the structural formulas? Explain.

When concentrated hydrochloric acid is added to a red solution containing the \(\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) complex ion, the solution turns blue as the tetrahedral \(\mathrm{CoCl}_{4}{ }^{2-}\) complex ion forms. Explain this color change.

Iron is present in the earth's crust in many types of minerals. The iron oxide minerals are hematite \(\left(\mathrm{Fe}_{2} \mathrm{O}_{3}\right)\) and magnetite \(\left(\mathrm{Fe}_{3} \mathrm{O}_{4}\right)\). What is the oxidation state of iron in each mineral? The iron ions in magnetite are a mixture of \(\mathrm{Fe}^{2+}\) and \(\mathrm{Fe}^{3+}\) ions. What is the ratio of \(\mathrm{Fe}^{3+}\) to \(\mathrm{Fe}^{2+}\) ions in magnetite? The formula for magnetite is often written as \(\mathrm{FeO} \cdot \mathrm{Fe}_{2} \mathrm{O}_{3} .\) Does this make sense? Explain.

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