Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
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Get started for freeBesides the central atom, what are the differences between \(\mathrm{CO}_{2}\) and \(\mathrm{SiO}_{2}\) ?
Carbon and sulfur form compounds with the formulas \(\mathrm{CS}_{2}\) and \(\mathrm{C}_{3} \mathrm{~S}_{2} .\) Draw Lewis structures and predict the shapes of these two compounds.
Many structures of phosphorus-containing compounds are drawn with some \(\mathrm{P}=\mathrm{O}\) bonds. These bonds are not the typical \(\pi\) bonds we've considered, which involve the overlap of two \(p\) orbitals. Instead, they result from the overlap of a \(d\) orbital on the phosphorus atom with a \(p\) orbital on oxygen. This type of \(\pi\) bonding is sometimes used as an explanation for why \(\mathrm{H}_{3} \mathrm{PO}_{3}\) has the first structure below rather than the second: Draw a picture showing how a \(d\) orbital and a \(p\) orbital overlap to form a \(\pi\) bond.
Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted directly using an iron mesh impregnated with oxides as a catalyst. For the reaction $$\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)$$ equilibrium constants \(\left(K_{\mathrm{p}}\right.\) values) as a function of temperature are \(300^{\circ} \mathrm{C}, \quad 4.34 \times 10^{-3}\) \(500^{\circ} \mathrm{C}, \quad 1.45 \times 10^{-5}\) \(600^{\circ} \mathrm{C}, \quad 2.25 \times 10^{-6}\) Is the reaction exothermic or endothermic?
One harmful effect of acid rain is the deterioration of structures and statues made of marble or limestone, both of which are essentially calcium carbonate. The reaction of calcium carbonate with sulfuric acid yields carbon dioxide, water, and calcium sulfate. Because calcium sulfate is marginally soluble in water, part of the object is washed away by the rain. Write a balanced chemical equation for the reaction of sulfuric acid with calcium carbonate.
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