Chapter 20: Problem 31
Write equations describing the reactions of Ga with each of the following: \(\mathrm{F}_{2}, \mathrm{O}_{2}, \mathrm{~S}\), and \(\mathrm{HCl}\).
Chapter 20: Problem 31
Write equations describing the reactions of Ga with each of the following: \(\mathrm{F}_{2}, \mathrm{O}_{2}, \mathrm{~S}\), and \(\mathrm{HCl}\).
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Get started for freeMany structures of phosphorus-containing compounds are drawn with some \(\mathrm{P}=\mathrm{O}\) bonds. These bonds are not the typical \(\pi\) bonds we've considered, which involve the overlap of two \(p\) orbitals. Instead, they result from the overlap of a \(d\) orbital on the phosphorus atom with a \(p\) orbital on oxygen. This type of \(\pi\) bonding is sometimes used as an explanation for why \(\mathrm{H}_{3} \mathrm{PO}_{3}\) has the first structure below rather than the second: Draw a picture showing how a \(d\) orbital and a \(p\) orbital overlap to form a \(\pi\) bond.
The inert-pair effect is sometimes used to explain the tendency of heavier members of Group \(3 \mathrm{~A}\) to exhibit \(+1\) and \(+3\) oxidation states. What does the inert-pair effect reference? (Hint: Consider the valence electron configuration for Group \(3 \mathrm{~A}\) elements.)
Use bond energies (Table 8.4) to show that the preferred products for the decomposition of \(\mathrm{N}_{2} \mathrm{O}_{3}\) are \(\mathrm{NO}_{2}\) and \(\mathrm{NO}\) rather than \(\mathrm{O}_{2}\) and \(\mathrm{N}_{2} \mathrm{O}\). (The \(\mathrm{N}-\mathrm{O}\) single bond energy is \(201 \mathrm{~kJ} / \mathrm{mol} .\) ) Hint: Consider the reaction kinetics.
The \(\mathrm{N}_{2} \mathrm{O}\) molecule is linear and polar. a. On the basis of this experimental evidence, which arrangement, NNO or NON, is correct? Explain your answer. b. On the basis of your answer to part a, write the Lewis structure of \(\mathrm{N}_{2} \mathrm{O}\) (including resonance forms). Give the formal charge on each atom and the hybridization of the central atom. c. How would the multiple bonding in $$: \mathrm{N} \equiv \mathrm{N}-\mathrm{O}$$ be described in terms of orbitals?
One reason suggested to account for the instability of long chains of silicon atoms is that the decomposition involves the transition state shown below: The activation energy for such a process is \(210 \mathrm{~kJ} / \mathrm{mol}\), which is less than either the \(\mathrm{Si}-\mathrm{Si}\) or \(\mathrm{Si}-\mathrm{H}\) energy. Why would a similar mechanism not be expected to be very important in the decomposition of long carbon chains?
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