Chapter 20: Problem 26
What ions are found in hard water? What happens when water is "softened"?
Chapter 20: Problem 26
What ions are found in hard water? What happens when water is "softened"?
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Get started for freeWrite equations describing the reactions of Sn with each of the following: \(\mathrm{Cl}_{2}, \mathrm{O}_{2}\), and \(\mathrm{HCl}\).
Beryllium shows some covalent characteristics in some of its compounds, unlike the other alkaline earth halides. Give a possible explanation for this phenomenon.
Give the Lewis structure, molecular structure, and hybridization of the oxygen atom for \(\mathrm{OF}_{2}\). Would you expect \(\mathrm{OF}_{2}\) to be a strong oxidizing agent like \(\mathrm{O}_{2} \mathrm{~F}_{2}\) discussed in Exercise \(67 ?\)
Halogens form a variety of covalent compounds with each other. For example, chlorine and fluorine form the compounds CIF, \(\mathrm{ClF}_{3}\), and \(\mathrm{ClF}_{5}\). Predict the molecular structure (including bond angles) for each of these three compounds. Would you expect \(\mathrm{FCl}_{3}\) to be a stable compound? Explain.
Although nitrogen trifluoride \(\left(\mathrm{NF}_{3}\right)\) is a thermally stable compound, nitrogen triiodide \(\left(\mathrm{NI}_{3}\right)\) is known to be a highly explosive material. \(\mathrm{NI}_{3}\) can be synthesized according to the equation $$\mathrm{BN}(s)+3 \mathrm{IF}(g) \longrightarrow \mathrm{BF}_{3}(g)+\mathrm{NI}_{3}(g)$$ a. What is the enthalpy of formation for \(\mathrm{NI}_{3}(s)\) given the enthalpy of reaction ( \(-307 \mathrm{~kJ}\) ) and the enthalpies of formation for \(\mathrm{BN}(s)(-254 \mathrm{~kJ} / \mathrm{mol}), \mathrm{IF}(g)(-96 \mathrm{~kJ} / \mathrm{mol})\), and \(\mathrm{BF}_{3}(g)\) \((-1136 \mathrm{~kJ} / \mathrm{mol}) ?\) b. It is reported that when the synthesis of \(\mathrm{NI}_{3}\) is conducted using \(4 \mathrm{~mol} \mathrm{IF}\) for every \(1 \mathrm{~mol} \mathrm{BN}\), one of the by-products isolated is \(\left[\mathrm{IF}_{2}\right]^{+}\left[\mathrm{BF}_{4}\right]^{-}\). What are the molecular geometries of the species in this by-product? What are the hybridizations of the central atoms in each species in the by-product?
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