Question

Give the systematic name for the following compounds that are found in everyday life. a. \(\mathrm{H}_{2} \mathrm{~S}\) (rotten egg smell) b. \(\mathrm{SO}_{2}\) (smell of burnt matches) c. \(\mathrm{SF}_{6}\) (aerosol can propellant) d. \(\mathrm{Na}_{2} \mathrm{SO}_{3}\) (dried fruit preservative)

Short answer

The systematic names for the given compounds are as follows: a. \(\mathrm{H}_{2} \mathrm{S}\) - dihydrogen monosulfide b. \(\mathrm{SO}_{2}\) - sulfur dioxide c. \(\mathrm{SF}_{6}\) - sulfur hexafluoride d. \(\mathrm{Na}_{2} \mathrm{SO}_{3}\) - sodium sulfite

Step-by-step solution

To name the compound \(\mathrm{H}_{2} \mathrm{S}\), we first identify the elements in the compound: Hydrogen (H) and Sulfur (S). Since Hydrogen is bonded to a non-metal (Sulfur), the compound is a covalent compound. The prefix for two Hydrogen atoms is "di," and since there's only one Sulfur atom, we don't need a prefix for it. The IUPAC systematic name for H2S is dihydrogen monosulfide. #Step 2: Name SO2 compound#

To name the compound \(\mathrm{SO}_{2}\), we first identify the elements in the compound: Sulfur (S) and Oxygen (O). Again, since Sulfur and Oxygen are both non-metals, the compound is a covalent compound. Since there's only one Sulfur atom, we don't need a prefix for it. The prefix for two Oxygen atoms is "di." The IUPAC systematic name for SO2 is sulfur dioxide. #Step 3: Name SF6 compound#

To name the compound \(\mathrm{SF}_{6}\), we first identify the elements in the compound: Sulfur (S) and Fluorine (F). Since Sulfur and Fluorine are both non-metals, the compound is a covalent compound. There's only one Sulfur atom, so we don't need a prefix for it. The prefix for six Fluorine atoms is "hexa." The IUPAC systematic name for SF6 is sulfur hexafluoride. #Step 4: Name Na2SO3 compound#

To name the compound \(\mathrm{Na}_{2} \mathrm{SO}_{3}\), we first identify the elements in the compound: Sodium (Na), Sulfur (S), and Oxygen (O). Since Sodium is an alkali metal, this compound is an ionic compound. There are two Sodium atoms, one Sulfur atom, and three Oxygen atoms in the compound. For an ionic compound containing polyatomic anions, we usually use the anion's common name rather than IUPAC nomenclature. In this case, the anion (SO3) is called "sulfite". Since there is a 1:2 ratio of cations/anions, the compound is named by combining the cation's name (Sodium) with the anion's name (sulfite). The IUPAC systematic name for Na2SO3 is sodium sulfite.

Key concepts

Covalent Compounds

Covalent compounds are formed when two or more non-metal elements share electrons, creating a bond that holds the atoms together. They usually involve pairs of elements like oxygen, nitrogen, or carbon, which often form strong and stable connections. These compounds can vary significantly in complexity, ranging from simple molecules like water (\(\mathrm{H}_{2}\mathrm{O}\)) to large and complex biological macromolecules like proteins and DNA.

• Usually made up of non-metal elements
• Formed by sharing electrons
• Commonly have lower melting and boiling points compared to ionic compounds

The naming of covalent compounds relies on prefixes to indicate the number of atoms present. For instance, if a compound contains two oxygen atoms, the prefix 'di-' is used, as seen in sulfur dioxide (\(\mathrm{SO}_{2}\)). This systematic approach helps in consistently identifying and naming different covalent compounds.

Ionic Compounds

Ionic compounds arise from the electrical attraction between positively charged metal ions and negatively charged non-metal ions. They often form rigid crystal lattice structures, giving them distinctive properties such as high melting and boiling points.

• Composed of metals and non-metals
• Formed through the transfer of electrons
• Tend to dissolve well in water

A classic example is sodium chloride (\(\mathrm{NaCl}\)), where sodium (a metal) donates an electron to chlorine (a non-metal), resulting in a stable ionic compound. The systematic naming of ionic compounds involves stating the metal first followed by the non-metal with an altered ending, such as in sodium sulfite (\(\mathrm{Na}_{2}\mathrm{SO}_{3}\)), where we use the actual name of the polyatomic ion involved.

IUPAC Nomenclature

The International Union of Pure and Applied Chemistry (IUPAC) provides an internationally recognized set of rules for naming chemical compounds. This systematic nomenclature ensures that each compound has a clear and universally understood name. The importance of IUPAC lies in its ability to eliminate confusion in scientific communication.

• Standardized naming system for all chemical compounds
• Utilizes prefixes to indicate the number of atoms in covalent compounds
• Incorporates specific rules for ionic compounds and polyatomic ions

Using IUPAC nomenclature, compounds like sulfur hexafluoride \((\mathrm{SF}_6)\), which uses the prefix 'hexa-' to denote six fluorine atoms, can be clearly identified across the globe. This approach facilitates clear discussions between scientists regardless of language or regional differences.

Polyatomic Ions

Polyatomic ions are charged entities composed of two or more covalently bonded atoms, acting as a single unit. Unlike simple ions, they have a charge resulting from the combination of their constituent atoms. A common example is the sulfate ion (\(\mathrm{SO}_{3}^{2-}\)) found in compounds like sodium sulfite (\(\mathrm{Na}_{2}\mathrm{SO}_{3}\)). These ions play a significant role in chemistry, especially in the formation of ionic compounds.

• Contain more than one type of atom
• Covalently bonded but carry a charge
• Integral in determining the properties of ionic compounds

In naming these compounds, the name of the polyatomic ion is retained, such as 'sulfite' in sodium sulfite, to simplify communication and maintain consistency across descriptions of various substances.