Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
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These are the key concepts you need to understand to accurately answer the question.
Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeConsider the system $$\mathrm{A}(g) \longrightarrow \mathrm{B}(g)$$ at \(25^{\circ} \mathrm{C}\). a. Assuming that \(G_{\mathrm{A}}^{\circ}=8996 \mathrm{~J} / \mathrm{mol}\) and \(G_{\mathrm{B}}^{\circ}=11,718 \mathrm{~J} / \mathrm{mol}\), cal- culate the value of the equilibrium constant for this reaction. b. Calculate the equilibrium pressures that result if \(1.00 \mathrm{~mol} \mathrm{~A}(\mathrm{~g})\) at \(1.00\) atm and \(1.00 \mathrm{~mol} \mathrm{~B}(g)\) at \(1.00 \mathrm{~atm}\) are mixed at \(25^{\circ} \mathrm{C}\). c. Show by calculations that \(\Delta G=0\) at equilibrium.
As \(\mathrm{O}_{2}(I)\) is cooled at \(1 \mathrm{~atm}\), it freezes at \(54.5 \mathrm{~K}\) to form solid \(\mathrm{I}\). At a lower temperature, solid I rearranges to solid II, which has a different crystal structure. Thermal measurements show that \(\Delta H\) for the \(\mathrm{I} \rightarrow\) II phase transition is \(-743.1 \mathrm{~J} / \mathrm{mol}\), and \(\Delta S\) for the same transition is \(-17.0 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). At what temperature are solids I and II in equilibrium?
Which of the following processes are spontaneous? a. A house is built. b. A satellite is launched into orbit. c. A satellite falls back to earth. d. The kitchen gets cluttered.
Human DNA contains almost twice as much information as is needed to code for all the substances produced in the body. Likewise, the digital data sent from Voyager II contained one redundant bit out of every two bits of information. The Hubble space telescope transmits three redundant bits for every bit of information. How is entropy related to the transmission of information? What do you think is accomplished by having so many redundant bits of information in both DNA and the space probes?
What types of experiments can be carried out to determine whether a reaction is spontaneous? Does spontaneity have any relationship to the final equilibrium position of a reaction? Explain.
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