Chapter 10: Problem 23
When wet laundry is hung on a clothesline on a cold winter day, it will freeze but eventually dry. Explain.
Chapter 10: Problem 23
When wet laundry is hung on a clothesline on a cold winter day, it will freeze but eventually dry. Explain.
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Get started for free\(\mathrm{X}\) rays of wavelength \(2.63\) Å were used to analyze a crystal. The angle of first-order diffraction \((n=1\) in the Bragg equation) was \(15.55\) degrees. What is the spacing between crystal planes, and what would be the angle for second-order diffraction \((n=2)\) ?
Explain the following: You add \(100 \mathrm{~mL}\) water to a \(500-\mathrm{mL}\) round-bottom flask and heat the water until it is boiling. You remove the heat and stopper the flask, and the boiling stops. You then run cool water over the neck of the flask, and the boiling begins again. It seems as though you are boiling water by cooling it.
MnO has either the \(\mathrm{NaCl}\) type structure or the \(\mathrm{CsCl}\) type structure (see Exercise 67). The edge length of the \(\mathrm{MnO}\) unit cell is \(4.47 \times 10^{-8} \mathrm{~cm}\) and the density of \(\mathrm{MnO}\) is \(5.28 \mathrm{~g} / \mathrm{cm}^{3}\) a. Does \(\mathrm{Mn} \mathrm{O}\) crystallize in the \(\mathrm{NaCl}\) or the \(\mathrm{CsCl}\) type structure? b. Assuming that the ionic radius of oxygen is \(140 . \mathrm{pm}\), estimate the ionic radius of manganese.
Argon has a cubic closest packed structure as a solid. Assuming that argon has a radius of \(190 . \mathrm{pm}\), calculate the density of solid argon.
The molar heat of fusion of sodium metal is \(2.60 \mathrm{~kJ} / \mathrm{mol}\), whereas its heat of vaporization is \(97.0 \mathrm{~kJ} / \mathrm{mol}\). a. Why is the heat of vaporization so much larger than the heat of fusion? b. What quantity of heat would be needed to melt \(1.00 \mathrm{~g}\) sodium at its normal melting point? c. What quantity of heat would be needed to vaporize \(1.00 \mathrm{~g}\) sodium at its normal boiling point? d. What quantity of heat would be evolved if \(1.00 \mathrm{~g}\) sodium vapor condensed at its normal boiling point?
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