Chapter 6: Problem 62
List the hydrogen orbitals in increasing order of energy.
Short Answer
Expert verified
The hydrogen orbitals in order of increasing energy are 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, etc.
Step by step solution
01
Understand Atomic Orbitals
Atomic orbitals describe regions around the nucleus where electrons are likely to be found. They include s, p, d, and f orbitals, each with different shapes and energy levels.
02
Identify Principal Quantum Number (n)
The principal quantum number, denoted as 'n', indicates the main energy level or shell. For hydrogen, the orbitals with the same 'n' have similar energies, but they increase with higher 'n' values.
03
Examine the Energy Levels
For the hydrogen atom, the energies of orbitals depend solely on the principal quantum number 'n'. Hence, for a given 'n', orbitals s, p, d, and f within that energy level have the same energy.
04
List Orbitals by Increasing n
The order of energy for hydrogen orbitals based on 'n' is
1s < 2s = 2p < 3s = 3p = 3d < 4s = 4p = 4d = 4f.
Orbital energies increase with increasing 'n', and within the same 'n', they have equal energy.
05
Final Ordering of Hydrogen Orbitals
The list of hydrogen orbitals in order of increasing energy is: 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, and so on, continuing with higher 'n' levels.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with Vaia!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Atomic Orbitals
Imagine an electron as buzzing around the nucleus of an atom within a certain region. This region is called an atomic orbital. Atomic orbitals tell us where an electron is likely to be found most of the time.
Atomic orbitals are like clouds with distinct shapes and sizes depending on their type. There are several kinds, including:
Atomic orbitals are like clouds with distinct shapes and sizes depending on their type. There are several kinds, including:
- s-orbitals: They are spherical in shape.
- p-orbitals: They resemble dumbbells and have three orientations in space.
- d-orbitals: These have more complex shapes with five orientations.
- f-orbitals: These have even more complex shapes with seven orientations.
Principal Quantum Number
The principal quantum number, represented by the letter 'n', is like a label for the energy level of an electron within an atom. Think of it as a number that tells us the size of the electron's path around the nucleus.
It's akin to an address system, labeling each energy shell. The principal quantum number can only be a positive integer (1, 2, 3, ...). Here are some essential points:
It's akin to an address system, labeling each energy shell. The principal quantum number can only be a positive integer (1, 2, 3, ...). Here are some essential points:
- Larger 'n' values mean the orbital is further from the nucleus.
- As 'n' increases, the electron's energy also rises.
- In hydrogen, the orbitals are organized such that orbitals with the same 'n' have the same energy.
Energy Levels
Energy levels in hydrogen's orbitals are mainly determined by the principal quantum number 'n'. Unlike large atoms, where sublevels within the same shell can differ in energy, hydrogen simplifies this. For hydrogen, each energy level has:
1s < 2s = 2p < 3s = 3p = 3d < 4s = 4p = 4d = 4f.
For each increasing value of 'n', the orbitals carry the electrons further from the nucleus and to higher energy states. This predictable energy pattern helps chemists understand and predict chemical behavior.
- All orbitals in the same 'n' level having the same energy.
- Increasing energy with larger 'n'.
1s < 2s = 2p < 3s = 3p = 3d < 4s = 4p = 4d = 4f.
For each increasing value of 'n', the orbitals carry the electrons further from the nucleus and to higher energy states. This predictable energy pattern helps chemists understand and predict chemical behavior.
s, p, d, and f Orbitals
The different types of orbitals—s, p, d, and f—are characterized by their shapes and the number of orientations they can have:
- s-orbitals: Only one orientation, spherical, capable of holding 2 electrons.
- p-orbitals: Three orientations, dumbbell-shaped, capable of holding 6 electrons in total.
- d-orbitals: Five orientations with complex clover shapes, capable of holding 10 electrons.
- f-orbitals: Seven orientations with even more complex shapes, holding up to 14 electrons.