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What is an energy level? Explain the difference between ground state and excited state.

Short Answer

Expert verified
Energy levels are quantized electron states. Ground state is the lowest energy level, and excited states occur when electrons absorb energy to move to a higher level.

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01

Understanding Energy Levels

In atoms, energy levels are the allowed energies an electron can have. These are quantized, meaning electrons can only inhabit specific energy levels and not values in between. Think of these levels as rungs on a ladder, where electrons can reside at any rung but cannot exist in between them.
02

Ground State Definition

The ground state refers to the lowest energy level that an electron can occupy in an atom. This is the most stable energy position for electrons and where they naturally tend to be if no external energy is provided.
03

Excited State Definition

An excited state is when an electron absorbs energy and moves to a higher energy level than its ground state. This is a temporary state, as electrons will eventually lose energy and return to the ground state, emitting energy in the form of light or other electromagnetic radiation.
04

Understanding the Transition

Moving from the ground state to an excited state involves energy absorption. Conversely, moving from an excited state back to the ground state involves energy release. The energy difference between these states is precisely quantified and often results in observable phenomena such as the emission of light (e.g., in fireworks or neon signs).

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ground State
The ground state of an atom is the lowest energy level that an electron can occupy. Imagine this state as the bottom rung of a ladder. An electron in the ground state is as comfortable as it can be, stable and happy without any outside influence. This state is the default position for electrons when they haven't absorbed extra energy.

In this state, the electron has minimized its energy, making the atom itself more stable. That is why electrons in the ground state are less likely to participate in chemical reactions - they're in a safe and content position. Without an external force, such as heat or light, pushing the electron to a higher energy level, it will remain in this stable ground state. Understanding the ground state helps us appreciate how atoms typically exist in most natural conditions.
Excited State
When an electron in an atom gains energy, it can move from the stable ground state to an excited state. Picture this as an electron climbing to a higher rung on a ladder. This requires the absorption of energy, which can come from various sources like heat or light.

Once in an excited state, the electron is in a less stable, higher energy position. It's like balancing on a ladder step that doesn't feel as secure as the lower one. Being in this high-energy state is only a temporary situation for electrons. They want to return to stability, so they eventually release the absorbed energy and drop back down to the ground state.

This process is significant because the energy released often manifests as light or other forms of electromagnetic radiation. These transitions and their observable effects are at the heart of many everyday technologies, such as glowing neon lights and colorful fireworks.
Quantized Energy
When we say energy levels are quantized, we mean that electrons can only occupy specific energy levels associated with an atom. These levels can be thought of as fixed rungs on a ladder. Electrons cannot be between these rungs, emphasizing the idea that energy levels are discrete and separate.

This quantization concept is foundational because it dictates how electrons behave within an atom. Electrons can transition between these levels but only by absorbing or emitting specific amounts of energy, known as quanta.

Understanding quantized energy allows us to predict the behavior of electrons and the types of transitions they can make. It is why certain chemicals emit particular colors when energized, an insight that is used in everything from identifying elements in stars to developing new materials.
Electron Transitions
Electron transitions involve electrons shifting between different energy levels within an atom. This movement occurs through either gaining or losing energy. When an electron absorbs enough energy, it jumps from a lower energy level (ground state) to a higher one (excited state). This process is like climbing up the ladder we often use to visualize energy levels.

When the electron returns to the ground state, it releases energy. This release often visible as light is the key to many scientific and technological phenomena. For example, the colors seen in fireworks result from these transitions, with electrons releasing energy as they return to their ground state.

These transitions are not random but highly predictable, allowing scientists to determine which elements are present in an unknown substance through techniques like spectroscopy. Electron transitions thus provide not only practical applications but also deepen our understanding of atomic structure and behavior.

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Most popular questions from this chapter

The retina of a human eye can detect light when radiant energy incident on it is at least \(4.0 \times 10^{-17} \mathrm{~J}\). For light of 585 -nm wavelength, how many photons does this energy correspond to?

A particular form of electromagnetic radiation has a frequency of \(9.87 \times 10^{15} \mathrm{~Hz}\). (a) What is its wavelength in nanometers? In meters? (b) To what region of the electromagnetic spectrum would you assign it? (c) What is the energy (in joules) of one quantum of this radiation?

An electron in a hydrogen atom is excited from the ground state to the \(n=4\) state. Comment on the correctness of the following statements (true or false). (a) \(n=4\) is the first excited state. (b) It takes more energy to ionize (remove) the electron from \(n=4\) than from the ground state. (c) The electron is farther from the nucleus (on average) in \(n=4\) than in the ground state. (d) The wavelength of light emitted when the electron drops from \(n=4\) to \(n=1\) is longer than that from \(n=4\) to \(n=2\) (e) The wavelength the atom absorbs in going from \(n=1\) to \(n=4\) is the same as that emitted as it goes from \(n=4\) to \(n=1\)

The blue color of the sky results from the scattering of sunlight by molecules in the air. The blue light has a frequency of about \(7.5 \times 10^{14} \mathrm{~Hz}\). (a) Calculate the wavelength (in \(\mathrm{nm}\) ) associated with this radiation, and (b) calculate the energy (in joules) of a single photon associated with this frequency.

The first line of the Balmer series occurs at a wavelength of \(656.3 \mathrm{nm}\). What is the energy difference between the two energy levels involved in the emission that results in this spectral line?

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