Chapter 4: Problem 85
Calculate the volume in milliliters of a \(1.420 \mathrm{M} \mathrm{NaOH}\) solution required to titrate the following solutions: a) \(25.00 \mathrm{~mL}\) of a \(2.430 \mathrm{M} \mathrm{HCl}\) solution b) \(25.00 \mathrm{~mL}\) of a \(4.500 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) solution c) \(25.00 \mathrm{~mL}\) of a \(1.500 \mathrm{M} \mathrm{H}_{3} \mathrm{PO}_{4}\) solution
Short Answer
Step by step solution
Understanding the Reaction
Calculating Moles of Acid (HCl)
Calculating Moles of NaOH for HCl
Calculating Volume of NaOH for HCl
Calculating Moles of Acid (H2SO4)
Calculating Moles of NaOH for H2SO4
Calculating Volume of NaOH for H2SO4
Calculating Moles of Acid (H3PO4)
Calculating Moles of NaOH for H3PO4
Calculating Volume of NaOH for H3PO4
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Neutralization Reaction
In an acid-base titration, this concept is crucial. It involves adding a base (in this case, a sodium hydroxide NaOH solution) to an acid solution until the acid is completely neutralized.
A unique factor here is the number of protons (H+) each acid can donate. This affects how much base is required for neutralization:
- For hydrochloric acid (HCl), it is a monoprotic acid, meaning it releases one proton per molecule, thus reacting 1:1 with NaOH.
- Sulfuric acid (H₂SO₄) is diprotic—each molecule releases two protons. Hence, it requires twice the amount of NaOH for neutralization.
- Phosphoric acid (H₃PO₄) is triprotic, releasing three protons each, necessitating three times the NaOH amount for complete reaction.
Molarity
For example, when a solution of HCl is described as 2.430 M, it means there are 2.430 moles of HCl per liter of solution. Similarly, the 1.420 M NaOH solution contains 1.420 moles of sodium hydroxide per liter.
Stoichiometry
- For HCl + NaOH, the reaction is in a 1:1 stoichiometry, meaning one mole of HCl reacts with one mole of NaOH.
- For H₂SO₄ + NaOH, the stoichiometry is 1:2, where one mole of sulfuric acid needs two moles of NaOH for full neutralization.
- For H₃PO₄ + NaOH, it is a 1:3 stoichiometry, requiring three moles of NaOH per mole of phosphoric acid.
Volume Calculation
Let's break down the steps using HCl as an example:
- First, determine the moles of HCl present using its molarity and volume in liters.
- Knowing it's a 1:1 reaction, establish that the moles of NaOH needed equal the moles of HCl.
- Determine the volume of NaOH by dividing the moles required by its molarity (1.420 M), thus finding the titrant volume required.