Chapter 18: Problem 51
What is a coupled reaction? What is its importance in biological reactions?
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 18: Problem 51
What is a coupled reaction? What is its importance in biological reactions?
These are the key concepts you need to understand to accurately answer the question.
All the tools & learning materials you need for study success - in one app.
Get started for freeFor each pair of substances listed here, choose the one having the larger standard entropy value at \(25^{\circ} \mathrm{C}\). The same molar amount is used in the comparison. Explain the basis for your choice. (a) \(\operatorname{Li}(s)\) or \(\operatorname{Li}(l),(b) C_{2} H_{5} O H(l)\) or \(\mathrm{CH}_{3} \mathrm{OCH}_{3}(l)\) (Hint: Which molecule can hydrogen- (d) \(\mathrm{CO}(g)\) or \(\mathrm{CO}_{2}(g),\) (e) \(\mathrm{O}_{2}(g)\) bond?), (c) \(\operatorname{Ar}(g)\) or \(\operatorname{Xe}(g)\), or \(\mathrm{O}_{3}(g),(\mathrm{f}) \mathrm{NO}_{2}(g)\) or \(\mathrm{N}_{2} \mathrm{O}_{4}(g) .\)
Why is it more convenient to predict the direction of a reaction in terms of \(\Delta G_{\mathrm{sys}}\) instead of \(\Delta S_{\text {univ }}\) ? Under what conditions can \(\Delta G_{\mathrm{sys}}\) be used to predict the spontaneity of a reaction?
The \(\mathrm{pH}\) of gastric juice is about 1.00 and that of blood plasma is \(7.40 .\) Calculate the Gibbs free energy required to secrete a mole of \(\mathrm{H}^{+}\) ions from blood plasma to the stomach at \(37^{\circ} \mathrm{C}\).
Crystallization of sodium acetate from a supersaturated solution occurs spontaneously (see Figure 13.2 ). Based on this, what can you deduce about the signs of \(\Delta S\) and \(\Delta H ?\)
Arrange the following substances ( 1 mole each) in order of increasing entropy at \(25^{\circ} \mathrm{C}:\) (a) \(\mathrm{Ne}(g)\), (b) \(\mathrm{SO}_{2}(g),\) (c) \(\mathrm{Na}(s)\) (d) \(\mathrm{NaCl}(s)\) (e) \(\mathrm{H}_{2}(g)\). Give the reasons for your arrangement.
What do you think about this solution?
We value your feedback to improve our textbook solutions.