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What is a coupled reaction? What is its importance in biological reactions?

Short Answer

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Coupled reactions link an exergonic and an endergonic reaction to perform essential biological functions by using shared energy.

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01

Definition of Coupled Reaction

A coupled reaction is a chemical reaction where two different reactions occur simultaneously. One of these reactions is exergonic, meaning it releases energy, while the other is endergonic, meaning it requires energy. The energy released from the exergonic reaction is used to drive the endergonic reaction.
02

Structure of Coupled Reactions

Coupled reactions typically involve the transfer of energy carriers, such as ATP in biological systems. For instance, the breakdown of ATP to ADP and inorganic phosphate releases energy, which can then be utilized to drive a separate reaction that requires energy input.
03

Importance in Biological Systems

In biological systems, coupled reactions are crucial because they allow organisms to perform energetically unfavorable processes, such as biosynthesis, movement, and active transport. The coupling of a favorable reaction with an unfavorable one ensures the overall process proceeds spontaneously.

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Exergonic Reaction
Exergonic reactions are essential to understanding energy transfer in biological systems. These reactions release energy, often in the form of heat or light, and result in a decrease in the free energy of the system. Examples include burning fuel or the breakdown of glucose during cellular respiration. Exergonic reactions are spontaneous, meaning they can occur without external energy input. Importantly, the energy they release can be harnessed to perform work in the cell or to drive other reactions forward. Understanding these reactions helps explain how energy flows within biological systems and how cells perform various functions.
Endergonic Reaction
In contrast to exergonic reactions, endergonic reactions require an input of energy to proceed. During these reactions, the products have higher free energy than the reactants, making them non-spontaneous and dependent on an energy source. A classic biological example of an endergonic reaction is the synthesis of carbohydrates from carbon dioxide and water during photosynthesis. Such reactions, while energetically unfavorable, are crucial for life, as they enable the synthesis of essential compounds needed for cell function and growth. The coupling with exergonic reactions, such as those involving ATP, often makes these necessary processes possible.
ATP in Biological Systems
Adenosine triphosphate (ATP) is frequently described as the "energy currency" of the cell. It is crucial for transferring energy within biological systems. ATP's structure includes three phosphate groups, and the bonds between these phosphate groups hold significant energy. When ATP is hydrolyzed to ADP (adenosine diphosphate) and an inorganic phosphate, this energy is released, which can then be used to power endergonic reactions. In cells, ATP provides the necessary energy for processes like muscle contractions, nerve impulse propagation, and active transport, demonstrating its widespread biological significance.
Energy Transfer
Energy transfer in biological systems is often mediated by molecules such as ATP, which facilitate the movement of energy from one reaction to another. This transfer is key to maintaining the balance between energy-releasing and energy-absorbing reactions, allowing for efficient functioning of metabolic pathways. For example, during cellular respiration, energy extracted from nutrients is transferred to ATP, which then releases it to fuel various cellular activities. The concept of energy transfer is crucial to understanding how cells utilize and manage energy efficiently, ensuring survival and adaptability in various environments.
Biological Importance of Coupled Reactions
Coupled reactions are vital in biology because they allow organisms to accomplish tasks that require energy input, often making these processes viable when they otherwise wouldn't be. By linking exergonic reactions, which release energy, with endergonic reactions, which require energy, cells can drive processes that are energetically unfavorable. This coupling is central to many physiological functions, including muscle movement, nerve impulses, and biosynthesis of molecules. Without coupled reactions, essential biological processes would not be possible. This highlights both the complexity and the elegance of cellular energy management.

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Most popular questions from this chapter

For each pair of substances listed here, choose the one having the larger standard entropy value at \(25^{\circ} \mathrm{C}\). The same molar amount is used in the comparison. Explain the basis for your choice. (a) \(\operatorname{Li}(s)\) or \(\operatorname{Li}(l),(b) C_{2} H_{5} O H(l)\) or \(\mathrm{CH}_{3} \mathrm{OCH}_{3}(l)\) (Hint: Which molecule can hydrogen- (d) \(\mathrm{CO}(g)\) or \(\mathrm{CO}_{2}(g),\) (e) \(\mathrm{O}_{2}(g)\) bond?), (c) \(\operatorname{Ar}(g)\) or \(\operatorname{Xe}(g)\), or \(\mathrm{O}_{3}(g),(\mathrm{f}) \mathrm{NO}_{2}(g)\) or \(\mathrm{N}_{2} \mathrm{O}_{4}(g) .\)

Why is it more convenient to predict the direction of a reaction in terms of \(\Delta G_{\mathrm{sys}}\) instead of \(\Delta S_{\text {univ }}\) ? Under what conditions can \(\Delta G_{\mathrm{sys}}\) be used to predict the spontaneity of a reaction?

The \(\mathrm{pH}\) of gastric juice is about 1.00 and that of blood plasma is \(7.40 .\) Calculate the Gibbs free energy required to secrete a mole of \(\mathrm{H}^{+}\) ions from blood plasma to the stomach at \(37^{\circ} \mathrm{C}\).

Crystallization of sodium acetate from a supersaturated solution occurs spontaneously (see Figure 13.2 ). Based on this, what can you deduce about the signs of \(\Delta S\) and \(\Delta H ?\)

Arrange the following substances ( 1 mole each) in order of increasing entropy at \(25^{\circ} \mathrm{C}:\) (a) \(\mathrm{Ne}(g)\), (b) \(\mathrm{SO}_{2}(g),\) (c) \(\mathrm{Na}(s)\) (d) \(\mathrm{NaCl}(s)\) (e) \(\mathrm{H}_{2}(g)\). Give the reasons for your arrangement.

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