Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

In biological and medical applications, it is often necessary to study the autoionization of water at \(37^{\circ} \mathrm{C}\) instead of \(25^{\circ} \mathrm{C}\). Given that \(K_{\mathrm{w}}\) for water is \(2.5 \times 10^{-14}\) at \(37^{\circ} \mathrm{C},\) calculate the \(\mathrm{pH}\) of pure water at this temperature.

Short Answer

Expert verified
The pH of pure water at 37°C is approximately 6.80.

Step by step solution

01

Define the Relationship Between Kw and pH

The ion product of water, denoted as \(K_{\mathrm{w}}\), is the equilibrium constant for the autoionization of water. At any temperature, the relationship between \(K_{\mathrm{w}}\) and the concentration of hydrogen ions \([\mathrm{H}^+]\) in pure water can be expressed as: \[ K_{\mathrm{w}} = [\mathrm{H}^+][\mathrm{OH}^-] \] In pure water, the concentration of hydrogen ions is equal to the concentration of hydroxide ions, i.e., \([\mathrm{H}^+] = [\mathrm{OH}^-]\). Thus, \(K_{\mathrm{w}} = [\mathrm{H}^+]^2\).
02

Solve for Hydrogen Ion Concentration

To find \([\mathrm{H}^+]\), take the square root of \(K_{\mathrm{w}}\): \[ [\mathrm{H}^+] = \sqrt{K_{\mathrm{w}}} = \sqrt{2.5 \times 10^{-14}} \] Calculating this gives: \([\mathrm{H}^+] \approx 1.58 \times 10^{-7}\).
03

Calculate the pH Value

The \(\mathrm{pH}\) of a solution is defined as the negative logarithm (base 10) of the hydrogen ion concentration: \[ \mathrm{pH} = -\log_{10}([\mathrm{H}^+]) \] Substituting the value of \([\mathrm{H}^+]\) from the previous step, \( \mathrm{pH} = -\log_{10}(1.58 \times 10^{-7}) \), which approximately equals \(6.80\).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Kw (ion product of water)
The autoionization of water is a fundamental concept where water molecules spontaneously form hydrogen ions ([H+]) and hydroxide ions ([OH-]). This process is in equilibrium, and the equilibrium constant for this reaction is known as the ion product of water, or \( K_{\mathrm{w}} \).

At any given temperature, the expression for \( K_{\mathrm{w}} \) is \( K_{\mathrm{w}} = [\mathrm{H}^+][\mathrm{OH}^-] \). This represents the concentrations of hydrogen and hydroxide ions in pure water.
  • At room temperature (25°C), \( K_{\mathrm{w}} \) is typically \( 1.0 \times 10^{-14} \).
  • At 37°C, as in biological contexts, \( K_{\mathrm{w}} \) increases slightly to \( 2.5 \times 10^{-14} \).
In pure water, the concentrations of [H+] and [OH-] are equal, leading to \( K_{\mathrm{w}} = [\mathrm{H}^+]^2 \). This relationship is crucial for understanding pH calculations.
pH calculation
Understanding how to calculate pH involves knowing that the pH is determined by the concentration of hydrogen ions in a solution. The formula for pH is given by:

\[ \text{pH} = -\log_{10}([\mathrm{H}^+]) \]
This means you're taking the base-10 logarithm of the hydrogen ion concentration and then multiplying by -1.

For example, if you have calculated \([\mathrm{H}^+] \approx 1.58 \times 10^{-7}\) at 37°C, you would insert this value into the formula:
\[ \text{pH} = -\log_{10}(1.58 \times 10^{-7}) \]
The result of this calculation gives a pH of approximately 6.80.
  • This value indicates that pure water is slightly less neutral at 37°C due to the increased ion product.
  • Pure water is neutral when \([\mathrm{H}^+]=[\mathrm{OH}^-]\), aligning with \( \text{pH} = 7 \) at room temperature.
Hydrogen ion concentration
Calculating the hydrogen ion concentration is an essential step in understanding water's autoionization and its effect on pH. Given the equilibrium condition, in pure water, \([\mathrm{H}^+] = [\mathrm{OH}^-]\). This simplifies the expression for \( K_{\mathrm{w}} \) to:

\[ K_{\mathrm{w}} = [\mathrm{H}^+]^2 \]
To find \([\mathrm{H}^+] \), you take the square root of \( K_{\mathrm{w}} \):
\[ [\mathrm{H}^+] = \sqrt{K_{\mathrm{w}}} \]
At 37°C, with \( K_{\mathrm{w}} = 2.5 \times 10^{-14} \), the calculation is:
\[ [\mathrm{H}^+] = \sqrt{2.5 \times 10^{-14}} \approx 1.58 \times 10^{-7} \]
This concentration influences the pH, showing how variations in temperature cause changes in water's ionization and subsequent pH.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Tooth enamel is largely hydroxyapatite \(\left[\mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{3} \mathrm{OH}\right]\). When it dissolves in water (a process called demineralization), it dissociates as follows: $$ \mathrm{Ca}_{5}\left(\mathrm{PO}_{4}\right)_{3} \mathrm{OH} \longrightarrow 5 \mathrm{Ca}^{2+}+3 \mathrm{PO}_{4}^{3-}+\mathrm{OH}^{-} $$ The reverse process, called remineralization, is the body's natural defense against tooth decay. Acids produced from food remove the \(\mathrm{OH}^{-}\) ions and thereby weaken the enamel layer. Most toothpastes contain a fluoride compound such as \(\mathrm{NaF}\) or \(\mathrm{SnF}_{2}\). What is the function of these compounds in preventing tooth decay?

The \(K_{\mathrm{a}}\) for hydrofluoric acid is \(7.1 \times 10^{-4}\). Calculate the \(\mathrm{pH}\) of a \(0.15-M\) aqueous solution of hydrofluoric acid at \(25^{\circ} \mathrm{C}\).

What is the original molarity of an aqueous solution of ammonia \(\left(\mathrm{NH}_{3}\right)\) whose \(\mathrm{pH}\) is 11.22 at \(25^{\circ} \mathrm{C}\left(K_{\mathrm{b}}\right.\) for \(\left.\mathrm{NH}_{3}=1.8 \times 10^{-5}\right) ?\)

Compare the pH of a \(0.040 \mathrm{M} \mathrm{HCl}\) solution with that of a \(0.040 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) solution. (Hint: \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a strong acid; \(K_{2}\) for \(\mathrm{HSO}_{4}^{-}=1.3 \times 10^{-2}\).)

Which of the following is the stronger base: \(\mathrm{NF}_{3}\) or \(\mathrm{NH}_{3}\) ? (Hint: \(\mathrm{F}\) is more electronegative than \(\mathrm{H}\).)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free