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Calculate the mass in grams of hydrogen chloride produced when \(5.6 \mathrm{~L}\) of molecular hydrogen measured at STP react with an excess of molecular chlorine gas.

Short Answer

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18.23 grams of HCl are produced.

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01

Understand the Reaction

The reaction between molecular hydrogen (\(\text{H}_2\)) and molecular chlorine \((\text{Cl}_2)\) to produce hydrogen chloride \((\text{HCl})\) is given by the balanced equation: \(\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl}\). This tells us that one mole of hydrogen reacts with one mole of chlorine to produce two moles of hydrogen chloride.
02

Use STP Conditions to Determine Moles of Hydrogen

At standard temperature and pressure (STP), one mole of an ideal gas occupies \(22.4\text{ L}\). With \(5.6 \text{ L}\) of \(\text{H}_2\), the number of moles is calculated by: \(\text{moles of } \text{H}_2 = \frac{5.6 \text{ L}}{22.4 \text{ L/mol}} = 0.25 \text{ moles}\).
03

Calculate Moles of Hydrogen Chloride Produced

From the balanced equation: \(\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl}\), we see that each mole of \(\text{H}_2\) produces 2 moles of \(\text{HCl}\). Therefore, \(0.25\) moles of \(\text{H}_2\) will produce: \(0.25 \times 2 = 0.5 \text{ moles of HCl}\).
04

Convert Moles of HCl to Grams

The molar mass of \(\text{HCl}\) is calculated as \(1.01\text{ g/mol (H)} + 35.45\text{ g/mol (Cl)} = 36.46\text{ g/mol}\). The mass of \(0.5 \text{ moles of HCl}\) is \(0.5 \times 36.46 \text{ g/mol} \approx 18.23 \text{ g}\).

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reactions
A chemical reaction involves the transformation of one or more substances into different substances. In this exercise, hydrogen gas (\( \text{H}_2 \)) and chlorine gas (\( \text{Cl}_2 \)) react to form hydrogen chloride (\( \text{HCl} \)). This is represented by the balanced chemical equation: \( \text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl} \).

Balancing an equation ensures the same number of each type of atom on both sides. Here, one mole of \( \text{H}_2 \) reacts with one mole of \( \text{Cl}_2 \) to produce two moles of \( \text{HCl} \). This process follows the law of conservation of mass, indicating no atoms are lost or gained during the reaction. Understanding this helps identify how reactants convert to products.
Mole Concept
The mole concept is a fundamental idea in chemistry that helps quantify amounts in a chemical reaction. A mole is a unit that represents \( 6.022 \times 10^{23} \) particles, such as atoms or molecules.

In this problem, we calculate the number of moles of hydrogen gas based on its volume at standard temperature and pressure (STP), where 1 mole of gas occupies \( 22.4 \text{ L} \). With \( 5.6 \text{ L} \) of \( \text{H}_2 \), we find it corresponds to \( 0.25 \) moles. This value helps us determine how much product, \( \text{HCl} \), can be formed. Moles allow us to connect mass and volume to the particles involved in the reaction.
Ideal Gas Law
The ideal gas law is a useful tool to connect pressure, volume, and temperature of gases. The simple form used at STP (standard temperature and pressure) states that \( 1 \text{ mole} \) of an ideal gas occupies \( 22.4 \text{ L} \).

This principle helps us convert the given volume of hydrogen gas (\( 5.6 \text{ L} \)) to moles. It simplifies many stoichiometry problems involving gases, especially under standard conditions, by correlating the physical characteristics of gases with their chemical properties through the equation \( PV = nRT \). This allows for straightforward calculations when given volumes.
Molar Mass Calculation
Molar mass is the mass of one mole of a substance, often expressed in grams per mole. Calculating molar masses involves adding the atomic masses of all elements in a compound.

For \( \text{HCl} \), the molar mass is calculated by adding the atomic mass of hydrogen (\( 1.01 \text{ g/mol} \)) and chlorine (\( 35.45 \text{ g/mol} \)), resulting in \( 36.46 \text{ g/mol} \).

In the exercise, \( 0.5 \text{ moles} \) of \( \text{HCl} \) are produced. By multiplying by its molar mass, we find that the reaction yields approximately \( 18.23 \text{ g} \) of \( \text{HCl} \). Understanding molar mass connects the concept of moles with measurable quantities, such as mass.

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Most popular questions from this chapter

The running engine of an automobile produces carbon monoxide (CO), a toxic gas, at the rate of about \(188 \mathrm{~g}\) \(\mathrm{CO}\) per hour. A car is left idling in a poorly ventilated garage that is \(6.0 \mathrm{~m}\) long, \(4.0 \mathrm{~m}\) wide, and \(2.2 \mathrm{~m}\) high at \(20^{\circ} \mathrm{C}\). (a) Calculate the rate of CO production in \(\mathrm{mol} / \mathrm{min}\). (b) How long would it take to build up a lethal concentration of \(\mathrm{CO}\) of 1000 ppmv (parts per million by volume)?

A 2.5-L flask at \(15^{\circ} \mathrm{C}\) contains a mixture of \(\mathrm{N}_{2}\), \(\mathrm{He},\) and Ne at partial pressures of 0.32 atm for \(\mathrm{N}_{2}, 0.15\) atm for He, and 0.42 atm for Ne. (a) Calculate the total pressure of the mixture. (b) Calculate the volume in liters at STP occupied by He and Ne if the \(\mathrm{N}_{2}\) is removed selectively.

Sodium bicarbonate \(\left(\mathrm{NaHCO}_{3}\right)\) is called baking soda because, when heated, it releases carbon dioxide gas, which is responsible for the rising of cookies, some doughnuts, and cakes. (a) Calculate the volume (in liters) of \(\mathrm{CO}_{2}\) produced by heating \(5.0 \mathrm{~g}\) of \(\mathrm{NaHCO}_{3}\) at \(180^{\circ} \mathrm{C}\) and 1.3 atm. (b) Ammonium bicarbonate \(\left(\mathrm{NH}_{4} \mathrm{HCO}_{3}\right)\) has also been used for the same purpose. Suggest one advantage and one disadvantage of using \(\mathrm{NH}_{4} \mathrm{HCO}_{3}\) instead of \(\mathrm{NaHCO}_{3}\) for baking.

Under the same conditions of temperature and pressure, why does \(1 \mathrm{~L}\) of moist air weigh less than \(1 \mathrm{~L}\) of dry air?

Determine the excluded volume per mole and the total volume of the molecules in a mole for a gas consisting of molecules with radius 165 picometers (pm). [Note: To obtain the volume in liters, we must express the radius in decimeters (dm).]

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