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List the physical characteristics of gases.

Short Answer

Expert verified
Gases have indefinite shape and volume, are compressible, and their behavior is influenced by temperature changes and diffusion capabilities.

Step by step solution

01

Identify the Fundamental Properties

Gases have distinct fundamental properties that are important to recognize. These include mass, volume, pressure, and temperature. These properties define the state and behavior of a gas under different conditions.
02

Understand the Indefinite Shape and Volume

Unlike solids and liquids, gases do not have a definite shape or a fixed volume. Gases take the shape and volume of their container, expanding or compressing to fill the available space. This characteristic is due to the weak intermolecular forces in gases.
03

Explore Compressibility

Gases are highly compressible compared to liquids and solids. This means that when pressure is applied, the molecules in a gas can be pushed closer together, reducing the volume of the gas significantly.
04

Examine the Effect of Temperature on Gas Behavior

The behavior of gases is highly dependent on temperature. Increasing the temperature increases the kinetic energy of gas molecules, causing them to move more rapidly and exert more pressure. Conversely, decreasing the temperature lowers kinetic energy, slowing molecular motion.
05

Consider Gas Mixtures and Diffusion

Gases can easily mix with one another to form homogenous mixtures due to the rapid motion of their molecules. This leads to the phenomenon of diffusion, where gas molecules spread out to evenly occupy the available space.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Compressibility of Gases
Gases are known for their remarkable ability to be compressed. This means that the volume of gas can be significantly reduced when pressure is applied.
  • The molecules in a gas are spaced far apart compared to liquids and solids.
  • When we apply pressure, these molecules are pushed closer together, decreasing the overall volume of the gas.
  • This behavior is mainly due to the weak or negligible intermolecular forces between gas molecules.
Compressibility is especially important in various applications, like in aerosol cans or in pumping air into vehicle tires, where gases are stored under high pressure. The ability to compress gases allows them to be easily stored and transported.
Temperature Effect on Gases
Temperature plays a crucial role in the behavior of gases. Changes in temperature can have a significant impact on the properties of gases.
  • As temperature increases, the kinetic energy of gas molecules also increases.
  • This causes the molecules to move more rapidly, which can result in more frequent collisions with the walls of their container, increasing pressure.
Conversely, when the temperature decreases, molecular motion slows down, reducing pressure and sometimes even causing gases to condense into liquids if the temperature is low enough. This relationship is captured by the ideal gas law, which relates pressure, volume, and temperature.
Gas Diffusion
Gas diffusion refers to the process where gas molecules spread out to uniformly fill their container.
  • This happens because gas molecules are constantly in motion, moving randomly at high speeds.
  • Diffusion is driven by the natural tendency of particles to move from areas of higher concentration to areas of lower concentration until a uniform distribution is reached.
An everyday example of gas diffusion is the spreading aroma of perfume in a room. Over time, the fragrance molecules spread out to occupy the entire space, due to diffusion.
Indefinite Shape and Volume of Gases
One of the most distinctive characteristics of gases is their lack of definite shape and volume.
  • Unlike solids with fixed shapes or liquids with definite volume, gases adapt to the shape and size of their container.
  • This is possible because gas molecules are not bound by strong intermolecular forces and are free to move independently.
For example, when a gas is introduced into a balloon, it will expand to fill the entire balloon, regardless of its initial volume or shape. This property is very useful in applications like airbags in cars, where gases rapidly expand to fill the available space during a crash.

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Most popular questions from this chapter

Dry ice is solid carbon dioxide. A \(0.050-\mathrm{g}\) sample of dry ice is placed in an evacuated 4.6-L vessel at \(30^{\circ} \mathrm{C}\). Calculate the pressure inside the vessel after all the dry ice has been converted to \(\mathrm{CO}_{2}\) gas.

Estimate the distance (in \(\mathrm{nm}\) ) between molecules of water vapor at \(100^{\circ} \mathrm{C}\) and \(1.0 \mathrm{~atm} .\) Assume ideal behavior. Repeat the calculation for liquid water at \(100^{\circ} \mathrm{C},\) given that the density of water is \(0.96 \mathrm{~g} / \mathrm{cm}^{3}\) at that temperature. Comment on your results. (Assume each water molecule to be a sphere with a diameter of \(0.3 \mathrm{nm} .\) ) (Hint: First calculate the number density of water molecules. Next, convert the number density to linear density, that is, the number of molecules in one direction.)

State Dalton's law of partial pressures and explain what mole fraction is. Does mole fraction have units?

A 2.5-L flask at \(15^{\circ} \mathrm{C}\) contains a mixture of \(\mathrm{N}_{2}\), \(\mathrm{He},\) and Ne at partial pressures of 0.32 atm for \(\mathrm{N}_{2}, 0.15\) atm for He, and 0.42 atm for Ne. (a) Calculate the total pressure of the mixture. (b) Calculate the volume in liters at STP occupied by He and Ne if the \(\mathrm{N}_{2}\) is removed selectively.

Apply your knowledge of the kinetic theory of gases to the following situations. (a) Two flasks of volumes \(V_{1}\) and \(V_{2}\left(V_{2}>V_{1}\right)\) contain the same number of helium atoms at the same temperature. (i) Compare the rootmean-square (rms) speeds and average kinetic energies of the helium (He) atoms in the flasks. (ii) Compare the frequency and the force with which the He atoms collide with the walls of their containers. (b) Equal numbers of He atoms are placed in two flasks of the same volume at temperatures \(T_{1}\) and \(T_{2}\left(T_{2}>T_{1}\right) .\) (i) Compare the rms speeds of the atoms in the two flasks. (ii) Compare the frequency and the force with which the He atoms collide with the walls of their containers. (c) Equal numbers of He and neon (Ne) atoms are placed in two flasks of the same volume, and the temperature of both gases is \(74^{\circ} \mathrm{C}\). Comment on the validity of the following statements: (i) The rms speed of He is equal to that of Ne. (ii) The average kinetic energies of the two gases are equal. (iii) The rms speed of each He atom is \(1.47 \times 10^{3} \mathrm{~m} / \mathrm{s}\)

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