Chapter 8: Problem 45
Write electron configurations for the most stable ion formed by each of the elements Al, Ba, Se, and I (when in stable ionic compounds).
Chapter 8: Problem 45
Write electron configurations for the most stable ion formed by each of the elements Al, Ba, Se, and I (when in stable ionic compounds).
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Get started for freeFor each of the following, write an equation that corresponds to the energy given. a. lattice energy of \(\mathrm{NaCl}\) b. lattice energy of \(\mathrm{NH}_{4} \mathrm{Br}\) c. lattice energy of \(\mathrm{MgS}\) d. \(\mathrm{O}=\mathrm{O}\) double bond energy beginning with \(\mathrm{O}_{2}(g)\) as a reactant
Which of the following compounds or ions exhibit resonance? a. \(\mathrm{O}_{3} \quad\) d. \(\mathrm{CO}_{3}^{2-}\) b. \(\mathrm{CNO}^{-} \quad\) e. \(\mathrm{AsF}_{3}\) c. \(\mathrm{AsI}_{3}\)
\(\mathrm{SF}_{6}, \mathrm{ClF}_{5},\) and \(\mathrm{XeF}_{4}\) are three compounds whose central atoms do not follow the octet rule. Draw Lewis structures for these compounds.
Think of forming an ionic compound as three steps (this is a simplification, as with all models): (1) removing an electron from the metal; (2) adding an electron to the nonmetal; and (3) allowing the metal cation and nonmetal anion to come together. a. What is the sign of the energy change for each of these three processes? b. In general, what is the sign of the sum of the first two processes? Use examples to support your answer. c. What must be the sign of the sum of the three processes? d. Given your answer to part c, why do ionic bonds occur? e. Given your above explanations, why is NaCl stable but not \(\mathrm{Na}_{2} \mathrm{Cl} ? \mathrm{NaCl}_{2} ?\) What about MgO compared to \(\mathrm{MgO}_{2} ? \mathrm{Mg}_{2} \mathrm{O} ?\)
Use bond energies (Table \(8.5 ),\) values of electron affinities (Table 7.7\()\) , and the ionization energy of hydrogen \((1312 \mathrm{kJ} / \mathrm{mol})\) to estimate \(\Delta H\) for each of the following reactions. a. \(\mathrm{HF}(g) \rightarrow \mathrm{H}^{+}(g)+\mathrm{F}^{-}(g)\) b. \(\mathrm{HCl}(g) \rightarrow \mathrm{H}^{+}(g)+\mathrm{Cl}^{-}(g)\) c. \(\mathrm{HI}(g) \rightarrow \mathrm{H}^{+}(g)+\mathrm{I}^{-}(g)\) d. \(\mathrm{H}_{2} \mathrm{O}(g) \rightarrow \mathrm{H}^{+}(g)+\mathrm{OH}^{-}(g)\)
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