Chapter 6: Problem 4
Liquid water turns to ice. Is this process endothermic or exothermic? Explain what is occurring using the terms system, surroundings, heat, potential energy, and kinetic energy in the discussion.
Chapter 6: Problem 4
Liquid water turns to ice. Is this process endothermic or exothermic? Explain what is occurring using the terms system, surroundings, heat, potential energy, and kinetic energy in the discussion.
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Get started for freeIt takes 585 \(\mathrm{J}\) of energy to raise the temperature of 125.6 \(\mathrm{g}\) mercury from \(20.0^{\circ} \mathrm{C}\) to \(53.5^{\circ} \mathrm{C}\) . Calculate the specific heat capacity and the molar heat capacity of mercury.
Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and hydrogen are combusted, carbon dioxide and water are the products. Using the enthalpies of combustion for \(\mathrm{C}_{4} \mathrm{H}_{4}(-2341 \mathrm{kJ} / \mathrm{mol}), \mathrm{C}_{4} \mathrm{H}_{8}\) \((-2755 \mathrm{kJ} / \mathrm{mol}),\) and \(\mathrm{H}_{2}(-286 \mathrm{kJ} / \mathrm{mol}),\) calculate \(\Delta H\) for the reaction $$ \mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) $$
On Easter Sunday, April \(3,1983,\) nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: $$ 2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g) $$ a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times\) \(10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0\(\% \mathrm{HNO}_{3}\) by mass with a density of 1.42 \(\mathrm{g} / \mathrm{cm}^{3} .\) What mass of sodium car- bonate was required for complete neutralization of the spill, and what quantity of heat was evolved? ( \(\Delta H_{\mathrm{f}}^{\circ}\) for \(\mathrm{NaNO}_{3}(a q)=-467 \mathrm{kJ} / \mathrm{mol} )\) b. According to The Denver Post for April \(4,1983,\) authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ},\) what was their major concern?
Consider the reaction $$ 2 \mathrm{HCl}(a q)+\mathrm{Ba}(\mathrm{OH})_{2}(a q) \longrightarrow \mathrm{BaCl}_{2}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ $$ \Delta H=-118 \mathrm{kJ} $$ Calculate the heat when 100.0 \(\mathrm{mL}\) of 0.500\(M \mathrm{HCl}\) is mixed with 300.0 \(\mathrm{mL}\) of 0.100\(M \mathrm{Ba}(\mathrm{OH})_{2}\) . Assuming that the temperature of both solutions was initially \(25.0^{\circ} \mathrm{C}\) and that the final mixture has a mass of 400.0 \(\mathrm{g}\) and a specific heat capacity of 4.18 \(\mathrm{J} / \mathrm{C} \cdot \mathrm{g}\) , calculate the final temperature of the mixture.
A sample of an ideal gas at 15.0 atm and 10.0 \(\mathrm{L}\) is allowed to expand against a constant external pressure of 2.00 atm at a constant temperature. Calculate the work in units of kJ for the gas expansion. (Hint: Boyle's law applies.)
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