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How is average bond strength related to relative potential energies of the reactants and the products?

Short Answer

Expert verified
The average bond strength in a chemical reaction is related to the relative potential energies of the reactants and products, such that if the average bond strength increases during the reaction, the potential energy of the products is lower than that of the reactants. Conversely, if the average bond strength decreases, the potential energy of the products is higher than that of the reactants. This is because stronger bonds are more stable and require more energy to break, leading to a decrease in potential energy when bond strength increases.

Step by step solution

01

Understand the terms potential energy and bond strength

Potential energy is the energy stored in a substance due to its chemical composition and the arrangement of its atoms. In a chemical reaction, potential energy may change as bonds between atoms are formed or broken. Bond strength, also known as bond energy, is a measure of the amount of energy required to break a chemical bond between two atoms. It is an indication of the stability of a chemical bond or a molecule. Stronger bonds have higher bond strengths, while weaker bonds have lower bond strengths.
02

Know the relationship between potential energy and bond strength

In a chemical reaction, the difference in potential energy between the reactants and the products is related to the bond strengths of the molecules involved. The potential energy of a system decreases when the bond strength of the molecules increases, as stronger bonds are more stable and require more energy to break.
03

Determine the reactants and products in a chemical reaction

For a given chemical reaction, identify the reactants and products involved. This will help us analyze the changes in potential energy and bond strengths between the initial state (reactants) and the final state (products).
04

Analyze the difference in bond strength between reactants and products

Calculate the differences in bond strength for each bond between the reactants and the products. This will help us to determine the overall change in bond strength during the chemical reaction.
05

Establish the relationship between average bond strength and potential energy changes

To find out the relationship between average bond strength and the relative potential energies of the reactants and products, we need to compare the changes in bond strength with the changes in potential energy. If the average bond strength increases during the reaction, the potential energy of the products should be lower than the potential energy of the reactants. Conversely, if the average bond strength decreases during the reaction, the potential energy of the products should be higher than the potential energy of the reactants. In conclusion, the average bond strength of the molecules in a chemical reaction is related to the relative potential energies of the reactants and the products. If the average bond strength increases during a chemical reaction, the potential energy of the products is lower than the potential energy of the reactants. If the average bond strength decreases during the reaction, the potential energy of the products is higher than the potential energy of the reactants.

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Most popular questions from this chapter

Nitromethane, \(\mathrm{CH}_{3} \mathrm{NO}_{2},\) can be used as a fuel. When the liquid is burned, the (unbalanced) reaction is mainly $$ \mathrm{CH}_{3} \mathrm{NO}_{2}(l)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+\mathrm{N}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ a. The standard enthalpy change of reaction \(\left(\Delta H_{\mathrm{rxn}}^{\circ}\right)\) for the balanced reaction (with lowest whole-number coefficients \()\) is \(-1288.5 \mathrm{kJ} .\) Calculate \(\Delta H_{\mathrm{f}}^{\circ}\) for nitromethane. b. A 15.0 -L flask containing a sample of nitromethane is filled with \(\mathrm{O}_{2}\) and the flask is heated to \(100 .^{\circ} \mathrm{C}\) . At this temperature, and after the reaction is complete, the total pressure of all the gases inside the flask is 950 . torr. If the mole fraction of nitrogen \(\left(\chi_{\text { nitrogen }}\right)\) is 0.134 after the reaction is complete, what mass of nitrogen was produced?

Consider the following equations: $$ \begin{array}{ll}{3 \mathrm{A}+6 \mathrm{B} \longrightarrow 3 \mathrm{D}} & {\Delta H=-403 \mathrm{kJ} / \mathrm{mol}} \\ {\mathrm{E}+2 \mathrm{F} \longrightarrow \mathrm{A}} & {\Delta H=-105.2 \mathrm{kJ} / \mathrm{mol}} \\\ {\mathrm{C} \longrightarrow \mathrm{E}+3 \mathrm{D}} & {\Delta H=64.8 \mathrm{kJ} / \mathrm{mol}}\end{array} $$ Suppose the first equation is reversed and multiplied by \(\frac{1}{6},\) the second and third equations are divided by \(2,\) and the three adjusted equations are added. What is the net reaction and what is the overall heat of this reaction?

Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and hydrogen are combusted, carbon dioxide and water are the products. Using the enthalpies of combustion for \(\mathrm{C}_{4} \mathrm{H}_{4}(-2341 \mathrm{kJ} / \mathrm{mol}), \mathrm{C}_{4} \mathrm{H}_{8}\) \((-2755 \mathrm{kJ} / \mathrm{mol}),\) and \(\mathrm{H}_{2}(-286 \mathrm{kJ} / \mathrm{mol}),\) calculate \(\Delta H\) for the reaction $$ \mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) $$

At 298 \(\mathrm{K}\) , the standard enthalpies of formation for \(\mathrm{C}_{2} \mathrm{H}_{2}(g)\) and \(\mathrm{C}_{6} \mathrm{H}_{6}(l)\) are 227 \(\mathrm{kJ} / \mathrm{mol}\) and \(49 \mathrm{kJ} / \mathrm{mol},\) respectively. a. Calculate \(\Delta H^{\circ}\) for $$ \mathrm{C}_{6} \mathrm{H}_{6}(l) \longrightarrow 3 \mathrm{C}_{2} \mathrm{H}_{2}(g) $$ b. Both acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) can be used as fuels. Which compound would liberate more energy per gram when combusted in air?

You have a 1.00 -mole sample of water at \(-30 .^{\circ} \mathrm{C}\) and you heat it until you have gaseous water at \(140 .^{\circ} \mathrm{C}\) . Calculate \(q\) for the entire process. Use the following data. $$ \begin{aligned} \text { Specific heat capacity of ice } &=2.03 \mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g} \\ \text { Specific heat capacity of water } &=4.18 \mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g} \\ \text { Specific heat capacity of steam } &=2.02 \mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g} \end{aligned} $$ $$ \mathrm{H}_{2} \mathrm{O}(s) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l) \quad \Delta H_{\mathrm{fision}}=6.02 \mathrm{kJ} / \mathrm{mol}\left(\mathrm{at} 0^{\circ} \mathrm{C}\right) $$ $$ \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(g) \quad \Delta H_{\mathrm{vaporization}}=40.7 \mathrm{kJ} / \mathrm{mol}\left(\mathrm{at} 100 .^{\circ} \mathrm{C}\right) $$

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