Chapter 6: Problem 13
Consider an airplane trip from Chicago, Illinois, to Denver, Colorado. List some path-dependent functions and some state functions for the plane trip.
Chapter 6: Problem 13
Consider an airplane trip from Chicago, Illinois, to Denver, Colorado. List some path-dependent functions and some state functions for the plane trip.
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Get started for freeAre the following processes exothermic or endothermic? a. When solid \(\mathrm{KBr}\) is dissolved in water, the solution gets colder. b. Natural gas \(\left(\mathrm{CH}_{4}\right)\) is burned in a furnace. c. When concentrated \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added to water, the solution gets very hot. d. Water is boiled in a teakettle.
In a coffee-cup calorimeter, 150.0 \(\mathrm{mL}\) of 0.50 \(\mathrm{M}\) HCl is added to 50.0 \(\mathrm{mL}\) of 1.00 \(\mathrm{M} \mathrm{NaOH}\) to make 200.0 \(\mathrm{g}\) solution at an initial temperature of \(48.2^{\circ} \mathrm{C}\) . If the enthalpy of neutralization for the reaction between a strong acid and a strong base is \(-56 \mathrm{kJ} / \mathrm{mol}\) , calculate the final temperature of the calorimeter contents. Assume the specific heat capacity of the solution is 4.184 \(\mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g}\) and assume no heat loss to the surroundings.
Using the following data, calculate the standard heat of formation of ICl \((g)\) in \(\mathrm{kJ} / \mathrm{mol} :\) $$\begin{array}{ll}{\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{Cl}(g)} & {\Delta H^{\circ}=242.3 \mathrm{kJ}} \\ {\mathrm{I}_{2}(g) \longrightarrow 2 \mathrm{I}(g)} & {\Delta H^{\circ}=151.0 \mathrm{kJ}} \\ {\mathrm{ICl}(g) \longrightarrow \mathrm{I}(g)+\mathrm{Cl}(g)} & {\Delta H^{\circ}=211.3 \mathrm{kJ}} \\ {\mathrm{I}_{2}(s) \longrightarrow \mathrm{I}_{2}(g)} & {\Delta H^{\circ}=62.8 \mathrm{kJ}}\end{array}$$
Which has the greater kinetic energy, an object with a mass of 2.0 \(\mathrm{kg}\) and a velocity of 1.0 \(\mathrm{m} / \mathrm{s}\) or an object with a mass of 1.0 \(\mathrm{kg}\) and a velocity of 2.0 \(\mathrm{m} / \mathrm{s}\) ?
Consider the reaction $$ 2 \mathrm{HCl}(a q)+\mathrm{Ba}(\mathrm{OH})_{2}(a q) \longrightarrow \mathrm{BaCl}_{2}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ $$ \Delta H=-118 \mathrm{kJ} $$ Calculate the heat when 100.0 \(\mathrm{mL}\) of 0.500\(M \mathrm{HCl}\) is mixed with 300.0 \(\mathrm{mL}\) of 0.100\(M \mathrm{Ba}(\mathrm{OH})_{2}\) . Assuming that the temperature of both solutions was initially \(25.0^{\circ} \mathrm{C}\) and that the final mixture has a mass of 400.0 \(\mathrm{g}\) and a specific heat capacity of 4.18 \(\mathrm{J} / \mathrm{C} \cdot \mathrm{g}\) , calculate the final temperature of the mixture.
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