Chapter 21: Problem 21
What causes high-altitude sickness, and what is high-altitude acclimatization?
Chapter 21: Problem 21
What causes high-altitude sickness, and what is high-altitude acclimatization?
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Get started for freeIron is present in the earth's crust in many types of minerals. The iron oxide minerals are hematite \(\left(\mathrm{Fe}_{2} \mathrm{O}_{3}\right)\) and magnetite \(\left(\mathrm{Fe}_{3} \mathrm{O}_{4}\right) .\) What is the oxidation state of iron in each mineral? The iron ions in magnetite are a mixture of \(\mathrm{Fe}^{2+}\) and Fe \(^{3+}\) ions. What is the ratio of \(\mathrm{Fe}^{3+}\) to \(\mathrm{Fe}^{2+}\) ions in magnetite? The formula for magnetite is often written as \(\mathrm{FeO} \cdot \mathrm{Fe}_{2} \mathrm{O}_{3} .\) Does this make sense? Explain.
A certain first-row transition metal ion forms many different colored solutions. When four coordination compounds of this metal, each having the same coordination number, are dissolved in water, the colors of the solutions are red, yellow, green, and blue. Further experiments reveal that two of the complex ions are paramagnetic with four unpaired electrons and the other two are diamagnetic. What can be deduced from this information about the four coordination compounds?
The complex ion \(\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) has an absorption maximum at around 800 \(\mathrm{nm}\) . When four ammonias replace water, \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}^{2+},\) the absorption maximum shifts to around 600 \(\mathrm{nm} .\) What do these results signify in terms of the relative field splittings of \(\mathrm{NH}_{3}\) and \(\mathrm{H}_{2} \mathrm{O}\) ? Explain.
A compound related to acetylacetone is 1,1,1-trifluoroacetylacetone (abbreviated Htfa): Htfa forms complexes in a manner similar to acetylacetone. (See Exercise 49.) Both Be \(^{2+}\) and \(\mathrm{Cu}^{2+}\) form complexes with tfa - having the formula \(\mathrm{M}(\mathrm{tfa})_{2}\) . Two isomers are formed for each metal complex. a. The Be \(^{2+}\) complexes are tetrahedral. Draw the two isomers of \(\mathrm{Be}(\mathrm{tfa})_{2} .\) What type of isomerism is exhibited by \(\mathrm{Be}(\mathrm{tfa})_{2} ?\) b. The \(\mathrm{Cu}^{2+}\) complexes are square planar. Draw the two isomers of \(\mathrm{Cu}(\mathrm{tfa})_{2} .\) What type of isomerism is exhibited by \(\mathrm{Cu}(\mathrm{tfa})_{2} ?\)
Acetylacetone (see Exercise \(45,\) part a), abbreviated acacH, is a bidentate ligand. It loses a proton and coordinates as acac\(^-\) as shown below: Acetylacetone reacts with an ethanol solution containing a salt of europium to give a compound that is 40.1\(\% \mathrm{C}\) and 4.71\(\% \mathrm{H}\) by mass. Combustion of 0.286 \(\mathrm{g}\) of the compound gives 0.112 \(\mathrm{g} \mathrm{Eu}_{2} \mathrm{O}_{3} .\) Assuming the compound contains only \(\mathrm{C}, \mathrm{H},\) O, and Eu, determine the formula of the compound formed from the reaction of acetylacetone and the europium salt. (Assume that the compound contains one europium ion.)
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