Chapter 21: Problem 20
Almost all metals in nature are found as ionic compounds in ores instead of being in the pure state. Why? What must be done to a sample of ore to obtain a metal substance that has desirable properties?
Chapter 21: Problem 20
Almost all metals in nature are found as ionic compounds in ores instead of being in the pure state. Why? What must be done to a sample of ore to obtain a metal substance that has desirable properties?
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Get started for freeSilver is sometimes found in nature as large nuggets; more often it is found mixed with other metals and their ores. Cyanide ion is often used to extract the silver by the following reaction that occurs in basic solution: $$\mathrm{Ag}(s)+\mathrm{CN}^{-}(a q)+\mathrm{O}_{2}(g) \stackrel{\mathrm{Basic}}{\longrightarrow} \mathrm{Ag}(\mathrm{CN})_{2}^{-}(a q)$$ Balance this equation by using the half-reaction method.
Draw the \(d\) -orbital splitting diagrams for the octahedral complex ions of each of the following. a. \(\mathrm{Zn}^{2+}\) b. \(\mathrm{Co}^{2+}\) (high and low spin) c. \(\mathrm{Ti}^{3+}\)
Oxalic acid is often used to remove rust stains. What properties of oxalic acid allow it to do this?
Compounds of copper(II) are generally colored, but compounds of copper(I) are not. Explain. Would you expect \(\mathrm{Cd}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\) to be colored? Explain.
Amino acids can act as ligands toward transition metal ions. The simplest amino acid is glycine \(\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}\right) .\) Draw a structure of the glycinate anion \(\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2}^{-}\right)\) acting as a bidentate ligand. Draw the structural isomers of the square planar complex \(\mathrm{Cu}\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2}\right)_{2}\)
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