The pH of human blood is steady at a value of approximately 7.4 owing to the
following equilibrium reactions:
$$
\mathrm{CO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons
\mathrm{H}_{2} \mathrm{CO}_{3}(a q) \rightleftharpoons \mathrm{HCO}_{3}^{-}(a
q)+\mathrm{H}^{+}(a q)
$$
Acids formed during normal cellular respiration react with the
\(\mathrm{HCO}_{3}^{-}\) to form carbonic acid, which is in equilibrium with
\(\mathrm{CO}_{2}(a q)\) and \(\mathrm{H}_{2} \mathrm{O}(l) .\) During vigorous
exercise, a person's \(\mathrm{H}_{2} \mathrm{CO}_{3}\) blood levels were \(26.3
\mathrm{mM},\) whereas his \(\mathrm{CO}_{2}\) levels were 1.63 \(\mathrm{mM}\) .
On resting, the \(\mathrm{H}_{2} \mathrm{CO}_{3}\) levels declined to 24.9
\(\mathrm{m} M\) . What was the \(\mathrm{CO}_{2}\) blood level at rest?