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What is the valence electron configuration of Group 6Aelements? What are some property differences between oxygen and polonium?

Short Answer

Expert verified

The valence electron configuration of Group 6Aelements isns2np4 .

The differences between oxygen and polonium are –

  • Oxygen is a non-metal and Polonium is a metal.
  • Oxygen is more electronegative than Polonium.
  • Polonium compound are formed in labs whereas oxygen can be found in natural compounds.

Step by step solution

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01

Concept Introduction

Electrons in an atom's outermost shell are known as valence electrons. The arrangement of electrons around the nucleus of an atom is known as electron configuration.

02

Electronic Configuration of Group 6A

The group electron configuration ofns2np4 suggests a group maximum oxidation number of+6 .

All the members of Group6Aother than oxygen are solids under normal conditions and, as we have seen previously, ametallic character generally increases down the group.

Oxygen, sulphur, and selenium are nonmetals, tellurium is a metalloid, and polonium is a metal.

Allotropy and polymorphism are important features of Group6Aand sulphur occurs in more natural allotropes andpolymorphs than any other element.

Therefore, the electronic configuration isns2np4 .

03

Difference between oxygen and polonium

In addition to its distinctive physical properties, oxygen is significantly different chemically from the other members of thegroup. It is the second most electronegative element in the periodic table and significantly more electronegative thanother elements in Group6A.

The electrical conductivities increase steadily down Group6Aas bonding changes from individual molecules (insulators)to metalloid networks (semiconductors) to a metallic solid (conductor).

Polonium is a very rare, radioactive metal.There are many different isotopes of polonium and all of the isotopes are radioactive.It dissolves easily into dilute acids. Polonium does not exist in nature in compounds, but it can form synthetic compoundsin the laboratory.

Therefore, the differences are nonmetal-metal, occurrence in natural compound and electronegativity.

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Most popular questions from this chapter

Hydrogen is produced commercially by the reaction of methane with steam:

CH4(g) +H2O(g)CO(g) + 3H2(g)

a. CalculateH0 andS0 for this reaction (use the data in Appendix ).

b. What temperatures will favour product formation assuming standard conditions and assuming thatH0 andS0 do not depend on temperature?

Nitrogen gas reacts with hydrogen gas to form ammonia gas (NH3). Consider the following illustration representing the original reaction mixture (the numbers of each molecule shown are relative numbers):

Assume this reaction mixture goes to completion. The piston apparatus allows the container volume to change in order to keep the pressure constant at 1.00atm. Assume ideal behaviour and constant temperature.

(a) What is the partial pressure of ammonia in the container when the reaction is complete?

(b) What is the mole fraction of ammonia in the container when the reaction is complete?

(c) What is the volume of the container when the reaction is complete?

Draw Lewis structures for the AsCl4+andAsCl6-ions. What type of reaction (acid–base, oxidation–reduction, or the like) is the following?

2AsCl5(g)AsCl4AsCl6(s)

Although nitrogenNF3is a thermally stable compound, nitrogen triiodideNF3is known to be a highly explosive material.NI3can be synthesized according to the equation

BN(s) + 3IF(g)BF3(g) + NI3(g)

  1. What is the enthalpy of formation for NI3(s) given the enthalpy of (-307kJ) and the enthalpies of formation for BN(s)(-254kJ/mol),IF(g)(-96kJ/mol) , and BF3(g)(-1136kJ/mol) ?
  2. It is reported that when the synthesis of NI3is conducted using 4 moles of IF for every 1 mole of BN, one of the by-products isolated is IF2+BF4-


What are the molecular geometries of the species in this by-product? What are the hybridizations of the central atoms in each species in the by-product?

Which of the following statement(s) is(are) true?

a. The alkali metals are found in the earth’s crust in the form of pure elements.

b. Gallium has one of the highest melting points known for metals.

c. When calcium metal reacts with water, one of the products is H2(g).

d. When AlCl3is dissolved in water, it produces an acidic solution.

e. Lithium reacts in the presence of excess oxygen gas to form lithium superoxide.

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