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When the environment is contaminated by a toxic or potentially toxic substance (for example, from a chemical spill or the use of insecticides), the substance tends to disperse. How is this consistent with the second law of thermodynamics? In terms of the second law, which requires the least work: cleaning the environment after it has been contaminated or trying to prevent the contamination before it occurs? Explain.

Short Answer

Expert verified

A much larger area has to be decontaminated if a substance gets dispersed.

Step by step solution

01

Definition of dispersion

A system in which distributed particles of one material are dispersed in a continuous phase of another material is defined as dispersion

02

Explanation

Due to the process of dispersion, the randomness increases. The entropy of the universe increases because it is a spontaneous process.

The work needs to be done to overcome this increased entropy. In terms of the second law of thermodynamics, it is more beneficial to prevent contamination of the environment rather than to clean it up later.

If a substance gets dispersed, a much larger area must be decontaminated.

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Most popular questions from this chapter

Consider 1.00โ€Šmoleโ€Šofโ€ŠCO2(g)โ€Šatโ€Š300โ€ŠKโ€Šandโ€Š5.00โ€Šatm. The gas expands until the final pressure is 1.00atm. For each of the following conditions describing the expansion, calculateq,wโ€Šandโ€Šฮ”E.Cpโ€Šforโ€ŠCO2โ€Šisโ€Š37.1JK-1mol-1, and assume that the gas behaves ideally.

  1. The expansion occurs isothermally and reversibly.
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Human DNA contains almost twice as much information as is needed to code for all the substances produced in the body. Likewise, the digital data sent from Voyager 2 contain one redundant bit out of every two bits of information. The Hubble space telescope transmits three redundant bits for every bit of information. How is entropy related to the transmission of information? What do you think is accomplished by having so many redundant bits of information in both DNA and the space probes?

Given the following illustration, what can be said about the sign of โˆ†Sfor the process of solid NaCl dissolving in water? What can be said forโˆ†H about this process?

127. Which of the following reactions (or processes) are expected to have a negative value for โˆ†So?
a. SiF6(aq)+H2(g)โ†’2HF(g)+SiF4(g)
b.4Al(s)+3O2(g)โ†’2Al2O3(s)
c.CO(g)+Cl2(g)โ†’COCl2(g)
d.C2H4(g)+H2O(l)โ†’C2H5OH(l)
e.H2O(s)โ†’H2O(l)

Using the data from appendix 4, calculate โˆ†Gfor the reaction 2H2S(g)+SO2(g)โ‡”3S(s)+2H2O(g)for the following conditions at 25ยฐC:

PH2s=1.0ร—10-4atmPSO2=1.0ร—10-2atmPH2O=3.0ร—10-2atm

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