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Using the phase diagram for water and Raoult’s law, explain why salt is spread on the roads in winter (even when the temperature is below freezing).

Short Answer

Expert verified

It lowers the melting point of the water.

Step by step solution

01

concept

If we add the salt on the top of ice, it dissolves in a thin layer of liquid water, which is always present on the top.

The solution of salt in the thin layer of liquid water has a lower melting point than pure water.

Ice in contact with the salty water then melts, create more salty water.

02

Step 2:Explain the reasoning

Using thephase diagram for waterif we move the melting point to the left, the state with the lowest energy on is then the liquid state.

Using the Raoult’s lawif we add a non-volatile solute, the mixture will have a lower boiling point than the pure solvent.

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Most popular questions from this chapter

From the following:

pure water

solution of C6 H12 O6 (x = 0.01) in water

solution of NaCl (x = 0.01) in water

solution of CaCl2 (x = 0.01) in water

Choose the one with the following:

a) highest freezing point

b) lowest freezing point

c) highest boiling point

d) lowest boiling point

e) highest osmotic pressure

A solution of phosphoric acid was made by dissolving 10.0 g of H3PO4 in 100.00 mL of water. The resulting volume was 104 mL. Calculate the density, mole fraction, molarity, and molality of the solution. Assume water has a density of 1.00 g/cm3.

A forensic chemist is given a white solid that is suspected of being pure cocaine C17H21NO4( molar mass 5 303.36 g/mol). She dissolves 1.22±0.01g of the solid in 15.60±0.01g of benzene. The freezing point is lowered by 1.32±0.048°C.

a. What is the molar mass of the substance? Assuming that the percentage of uncertainty in the calculated molar mass is the same as the percentage of uncertainty in the temperature change, calculate the uncertainty in the molar mass.

b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass 5 299.37)?

c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?

Which solvent water or carbon tetrachloride would you choose to dissolve each of the following?(a) KrF2

(b) SF2

(c) SO2

(d) CO2

(e) MgF2

(f) CH2O

(g) CH2=CH2

Plants that thrive in salt water must have internal solutions (inside the plant cells) that are isotonic (same osmotic pressure) with the surrounding solution. A leaf of a saltwater plant is able to thrive in an aqueous salt solutionat258oC that has a freezing point equal to20.6218oC . You would like to use this information to calculate the osmotic pressure of the solution in the cell.

a. In order to use the freezing-point depression to calculate osmotic pressure, what assumption must you make (in addition to the ideal behavior of the solutions, which we will assume)?

b. Under what conditions are the assumptions in part reasonable?

c. Solve for the osmotic pressure at258oCof the solution in the plant cell.

d. The plant leaf is placed in an aqueous salt solution at258oC that has a boiling point of 102.08C. What will happen to the plant cells in the leaf?

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