Chapter 21: Q98E (page 888)
How many different pentapeptides can be formed using five different amino acids?
Short Answer
There are 120 different pentapeptides are possible to form out of five different amino acids.
Chapter 21: Q98E (page 888)
How many different pentapeptides can be formed using five different amino acids?
There are 120 different pentapeptides are possible to form out of five different amino acids.
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Get started for freeIn 1994 chemists at Texas A\&M University reported the synthesis of a non-naturally occurring amino acid:
a. To which naturally occurring amino acid is this compound most similar?
b. A tetrapeptide, phe-met-arg-phe-is synthesized in the brains of rats addicted to morphine and heroin. (Theindicates that the peptide ends ininstead of.) The TAMU
scientists synthesized a similar tetrapeptide, with the synthetic amino acid above replacing one of the original amino acids. Draw a structure for the tetrapeptide containing the synthetic amino acid.
c. Indicate the chiral carbon atoms in the synthetic amino acid.
d. Draw the geometric isomers for this synthetic amino acid. (Hint: Refer to Exercise 25.)
Give an example reaction that would yield the following products as major organic products. For oxidation reactions, just write oxidation over the arrow and don’t worry about the actual reagent.
a. primary alcohol e. ketone
b. secondary alcohol f. carboxylic acid
c. tertiary alcohol g. ester
d. aldehyde
Give an example reaction that would yield the following products. Name the organic reactant and product in each reaction. a. alkane b. monohalogenated alkane c. di halogenated alkane d. tetra halogenated alkane e. monohalogenated benzene f. alkene
“Super glue” contains methyl cyanoacrylate,
which readily polymerizes on exposure to traces of water or alcohols on the surfaces to be bonded together. The polymer provides a strong bond between the two surfaces. Draw the structure of the polymer formed by methyl cyanoacrylate.
There are three isomers of dichlorobenzene, one of which has now replaced naphthalene as the main constituent of mothballs.
(a) Identify the ortho, meta, and para isomers of dichlorobenzene.
(b) Predict the number of isomers for trichlorobenzene.
(c) The presence of one chlorine atom on a benzene ring will cause the next substituent to add ortho orpara to the first chlorine atom on the benzene ring. What does this tell you about the synthesis of m-dichlorobenzene?
(d) Which of the isomers of trichlorobenzene will be the hardest to prepare?
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