Chapter 21: Q157AE (page 890)
Which of the amino acids in is/are not optically active?
Short Answer
Glycine is not optically active.
Chapter 21: Q157AE (page 890)
Which of the amino acids in is/are not optically active?
Glycine is not optically active.
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Get started for freeConsider the titration of 50.0 mL of 1.0 M glycine hydrochloride [(H3NCH2COOH)Cl], with 1.0 M NaOH.For +H3NCH2COOH, Ka for the carboxylic acid groupis and Kb for the amino group is .
a. Calculate the pH after 25.0 mL, 50.0 mL, and75.0 mL of NaOH has been added. Hint: Refer toSection 8.7 of the text, and treat the titration of+H3NCH2COOH as a diprotic acid titration.
b. Sketch the titration curve and indicate the majoramino acid species present after 0.0 mL, 25.0 mL,50.0 mL, 75.0 mL, and 100.0 mL of 1.0 M NaOHhave reacted completely. Assume the initial pH is1.2 and the pH at the second equivalence pointis 11.7.
c. At what pH do the majority of amino acid molecules have a net charge of zero? This pH is calledthe isoelectric point.
d. At what pH is the net charge of the major aminoacid species present equal to
For each of the following alcohols, give the systematic name and specify whether the alcohol is primary, secondary, or tertiary.
Draw the isomer(s) specified. There may be more than one possible isomer for each part.
a. a cyclic compound that is an isomer of trans-โ2 butene
b. an ester that is an isomer of propanoic acid
c. a ketone that is an isomer of butanal
d. a secondary amine that is an isomer of butylamine
e. a tertiary amine that is an isomer of butylamine
f. an ether that is an isomer of 2-methyl-2-propanol
g. a secondary alcohol that is an isomer of 2-methyl-2-propanol
Define and give an example of each of the following.
a. addition polymer d. Homopolymer
b. condensation polymer e. polyester
c. copolymer f. polyamide
Name the following compounds.
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