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Which of the amino acids in is/are not optically active?

Short Answer

Expert verified

Glycine is not optically active.

Step by step solution

01

Amino acids

The organic compounds that contain both carboxylic acid and amine group (in the alpha position) are called amino acids.

If they contain a chiral carbon then they are optically active.

02

Define Polyamide

All chiral molecules are optically active.

Chiral molecules are most often those molecules that contain an asymmetrically substituted carbon atom.

Unlike all other amino acids, the glycine doesn't have asymmetrically substituted carbon and therefore only glycine is optically inactive.

The structure of glycine is as shown below:

Therefore, Glycine is not optically active.

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Most popular questions from this chapter

Consider the titration of 50.0 mL of 1.0 M glycine hydrochloride [(H3NCH2COOH)Cl], with 1.0 M NaOH.For +H3NCH2COOH, Ka for the carboxylic acid groupis 4.3ร—10โˆ’3and Kb for the amino group is 6.0ร—10โˆ’5.

a. Calculate the pH after 25.0 mL, 50.0 mL, and75.0 mL of NaOH has been added. Hint: Refer toSection 8.7 of the text, and treat the titration of+H3NCH2COOH as a diprotic acid titration.

b. Sketch the titration curve and indicate the majoramino acid species present after 0.0 mL, 25.0 mL,50.0 mL, 75.0 mL, and 100.0 mL of 1.0 M NaOHhave reacted completely. Assume the initial pH is1.2 and the pH at the second equivalence pointis 11.7.

c. At what pH do the majority of amino acid molecules have a net charge of zero? This pH is calledthe isoelectric point.

d. At what pH is the net charge of the major aminoacid species present equal to+12?โˆ’12?

For each of the following alcohols, give the systematic name and specify whether the alcohol is primary, secondary, or tertiary.

Draw the isomer(s) specified. There may be more than one possible isomer for each part.

a. a cyclic compound that is an isomer of trans-โ€‘2 butene

b. an ester that is an isomer of propanoic acid

c. a ketone that is an isomer of butanal

d. a secondary amine that is an isomer of butylamine

e. a tertiary amine that is an isomer of butylamine

f. an ether that is an isomer of 2-methyl-2-propanol

g. a secondary alcohol that is an isomer of 2-methyl-2-propanol

Define and give an example of each of the following.

a. addition polymer d. Homopolymer

b. condensation polymer e. polyester

c. copolymer f. polyamide

Name the following compounds.

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