Chapter 21: 47-E (page 888)
Draw the structural formula for each of the following.
a. formaldehyde (methanal)
b. 4-heptanone
c. 3-chlorobutanal
d. 5,5-dimethyl-2-hexanone
Short Answer
a.
b.
c.
d.
Chapter 21: 47-E (page 888)
Draw the structural formula for each of the following.
a. formaldehyde (methanal)
b. 4-heptanone
c. 3-chlorobutanal
d. 5,5-dimethyl-2-hexanone
a.
b.
c.
d.
All the tools & learning materials you need for study success - in one app.
Get started for freeComplete the following reactions
Consider the titration of 50.0 mL of 1.0 M glycine hydrochloride [(H3NCH2COOH)Cl], with 1.0 M NaOH.For +H3NCH2COOH, Ka for the carboxylic acid groupis and Kb for the amino group is .
a. Calculate the pH after 25.0 mL, 50.0 mL, and75.0 mL of NaOH has been added. Hint: Refer toSection 8.7 of the text, and treat the titration of+H3NCH2COOH as a diprotic acid titration.
b. Sketch the titration curve and indicate the majoramino acid species present after 0.0 mL, 25.0 mL,50.0 mL, 75.0 mL, and 100.0 mL of 1.0 M NaOHhave reacted completely. Assume the initial pH is1.2 and the pH at the second equivalence pointis 11.7.
c. At what pH do the majority of amino acid molecules have a net charge of zero? This pH is calledthe isoelectric point.
d. At what pH is the net charge of the major aminoacid species present equal to
Polyesters containing double bonds are often crosslinked by reacting the polymer with styrene. This type of reaction is common in the manufacture of fiberglass. Draw the structure of the copolymer of
Aspartame, the artificial sweetener marketed under the name NutraSweet, is a methyl ester of a dipeptide. The structure of aspartame is
a. What two amino acids are used to prepare aspartame?
b. There is concern that methanol may be produced by the decomposition of aspartame. From what portion of the molecule can methanol be produced? Write an equation for this.
When pure crystalline amino acids are heated, decomposition generally occurs before the solid melts. Account for this observation.
(Hint: Crystalline amino acids exist ascalled zwitterions.
What do you think about this solution?
We value your feedback to improve our textbook solutions.