Chapter 16: Q39 E (page 704)
How could you tell experimentally if TiO2 is an ionic solid or a network solid?
Short Answer
Tio2 is an ionic solid. This can be checked by determining the conductivity of the compound.
Chapter 16: Q39 E (page 704)
How could you tell experimentally if TiO2 is an ionic solid or a network solid?
Tio2 is an ionic solid. This can be checked by determining the conductivity of the compound.
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MnO has either the NaCl type structure or the CsCl type structure. The edge length of the MnO unit cell is 4.47ร10-8 cm, and the density of MnO is 5.28 g/cm3.
a. Does MnO crystallize in the NaCl type or the CsCl type structure?
b. Assuming that the ionic radius of oxygen is 140. pm, estimate the ionic radius of manganese.
c. Does the calculated cation-to-anion radius ratio for MnO substantiate your answer in part a? Explain.
Carbon diselenide (CSe2) is a liquid at room temperature. The normal boiling point is 125oC and the melting point is -45.5o . Carbon disulfide (CS2) is also a liquid at room temperature, with normal boiling and melting points of 46.5oC and -111.6oC respectively. How do the strengths of the intermolecular forces vary from CO2 to CS2 to CSe2? Explain your answer.
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