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Consider the following phase diagram. What phases arepresent at points Athrough H? Identify the triple point,normal boiling point, normal freezing point, and criticalpoint. Which phase is denser, solid or liquid?

Short Answer

Expert verified

Point

Description

A

Solid-phase region

B

Liquid-phase region

C

Gas-phase region

D

Normal Freezingng point

E

Triple point

F

Normal Boiling point

G

Critical point

H

Supercritical fluid point

Step by step solution

01

The phases present in the given phase diagram

From points A through H, there are three phases included. The phases in the above phase diagram are solid, liquid, and gas.

If we see from point A to H, the phase change is given as

Region

Phase change

A to B

Solid to liquid

B to C

Liquid to gas

C to D

No change

D to E

Sublimation curve

E to F

Vapour pressure curve

F to G

Vapour pressure curve

G to H

Supercritical fluid

02

The points from the phase diagram

The points are described as follows-

Point

Description

A

Solid-phase region

B

Liquid-phase region

C

Gas-phase region

D

Normal Freezing point

E

Triple point

F

Normal Boiling point

G

Critical point

H

Supercritical fluid point

The solid phase is denser than the liquid as the slope of the solid-liquid equilibrium curve is positive. If the pressure rises, the molecules become more close to the volume of the sample decreases.

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Most popular questions from this chapter

Like most substances, bromine exists in one of the threetypical phases. Br2 has a normal melting point of -7.20Cand a normal boiling point of 59C. The triple point foris and 40 torrs, and the critical point is and 100 atm. Using this information, sketch a phase diagram for bromine indicating the points described above. Based on your phase diagram, order the three phases from least dense to most dense. What are the stable phase of Br2 at room temperature and 1 atm? Under what temperature conditions can liquid bromine never exist? What phase changes occur as the temperature of a sample of bromine at 0.10 atm is increased from-500C to 2000C ?

Define each of the following.

a. evaporation e. melting

b. condensation f. enthalpy of

vaporization

c. sublimation g. enthalpy of fusion

d. boiling h. heating curve

Consider a perfectly insulated and sealed container. Determine the minimum volume of a container such that a gallon of water at will evaporate completely. If the container is a cube, determine the dimensions in feet. Assume the density of water is0.998g/cm3.

A given sample of wรผstite has the formula Fe0.950O1.00. Calculate the fraction of iron ions present as Fe3+. What fraction of the sites normally occupied by Fe2+must be vacant in this solid?

MnO has either the NaCl type structure or the CsCl type structure. The edge length of the MnO unit cell is 4.47ร—10-8 cm, and the density of MnO is 5.28 g/cm3.

a. Does MnO crystallize in the NaCl type or the CsCl type structure?

b. Assuming that the ionic radius of oxygen is 140. pm, estimate the ionic radius of manganese.

c. Does the calculated cation-to-anion radius ratio for MnO substantiate your answer in part a? Explain.

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