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Is the following statement true or false? Concentration cells work because standard reduction potentials are dependent on concentration. Explain.

Short Answer

Expert verified

The given statement should betrue.Concentration cells work because standard reduction potentials are dependent on concentration.

Step by step solution

01

Definition of standard reduction potential

The tendency to measure a chemical substance reduction is called standard reduction potential. It must be compared to the 0.00 V potential of the standard hydrogen potential reference electrode. It can be expressed involts

02

Standard reduction potential depend on concentration

The working takes place due to the concentration dependence on standard reduction potential. There is a production of electricity from concentration cells which can be extracted using difference in concentration within same reaction

03

Production of energy from thermal source

The electricity can be produced from thermal energy. When the electricity passed from one cell to another, the cells can take up the heat. Due to the chemical concentration merging into two cells, it is possible to even without a temperature gradient which increases entropy and decreases entropy compensation on heat conversion.

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Most popular questions from this chapter

Use the table of standard reduction potentials (Table 11.1) to pick a reagent that is capable of each of the following reduction (under standard conditions in acidic solution).

a.reducesCu2+toCubut does not reduceCu2+toCu+.

b. reducesBr2toBr-but does not reduceI2toI-.

Calculate the maximum amount of work that can beobtained from the galvanic cells at standard conditionsin Exercise 22.

Question:Three electrochemical cells were connected in series so that the same quantity of electrical current passes through all three cells. In the first cell, 1.15 g of chromium metal was deposited from chromium (III) nitrate solution. In the second cell, 3.15 g of osmium was deposited from a solution made of Osn+ and nitrate ions. What is the name of the salt? In the third cell, the electrical charge passed through a solution containing X2+ ions caused deposition of 2.11 g of metallic X. Identify X.

Consider the concentration cell shown below. Calculate the cell potential at 25ยฐC when the concentration ofNi2+ in the compartment on the right has each of the following values.

a. 1.0 M

b. 2.0 M

c. 0.10 M

d. 4.0 x 10-5 M

e. Calculate the potential when bothsolutions are 2.5 M in Ni2+.

For each case, identify the cathode, the anode, and thedirection in which electrons flow.

Calculatevalues for the following cells. Which reactions are spontaneous as written (under standard conditions)? Balance the equations. Standard reduction potentials are found in Table 11.1.

a.MnO4-(aq)+I-(aq)โ‡„I2(aq)+Mn2+(aq)b.MnO4-(aq)+F-(aq)โ‡„F2(aq)+Mn2+(aq)c.H2(g)โ‡„H+(aq)+H-(aq)d.Au3+(aq)+Ag(s)โ‡„Ag+(aq)+Au(s)
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