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If the cell potential is proportional to work and the standard reduction potential for the hydrogen ion is zero, does this mean that the reduction of the hydrogen ion requires no work?

Short Answer

Expert verified

Whether when reduction of hydrogen ions works or not, this should be interpreted.

Step by step solution

01

Whether when reduction of hydrogen ions works or not, this should be interpreted.

The difference in potential between anode and cathode is called cell potential. The overall cell potential can be written as,

E0cell=E0(cathode)-E0(anode)

02

Relationship between change of Gibbs free energy and cell potential

The relation between change of Gibbs free energy and cell potential can be written as,

ΔGo=-nFEocell

Here, Gibbs free energy change isΔG0.

Number of electrons for N and F is considered as Faraday’s constant

03

Electrode potential of hydrogen is zero

The electrode potential is said to be zero when the hydrogen works as standard reference. The electrode’s potential needs to be measured. When there is an equilibrium cell reaction, the cell potential is zero. There is no work done when the cell reaction is in equilibrium.

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Most popular questions from this chapter

Chlorine dioxide (CIO2), which is produced by thereaction
2NaClO2aq+Cl2g2ClO2g+2NaClaq
has been tested as a disinfectant for municipal watertreatment.

  1. Using data from Table 11.1, calculateEo,ΔGoand K at 25°C for the production of ClO2.
  2. One of the concerns in using ClO2 as a disinfectant is that the carcinogenic chlorate ion (CIO3-) might be a by-product. It can be formed from the reaction
    ClO2gClO3-aq+Cl-aq
    Balance the equation for the decomposition of CIO2.

Electrolysis of an alkaline earth metal chloride using acurrent of 5.00 A for 748 seconds deposits 0.471 g ofmetal at the cathode. What is the identity of the alkaline earth metal chloride?

Sketch a galvanic cell, and explain how it works. Look at Figs. 11.1 and 11.2. Explain what is occurring in each container and why the cell in Fig. 11.2 “works” but the one in Fig. 11.1 does not.

Consider the following electrochemical cell:

a. If silver metal is a product of the reaction, is the cella galvanic cell or electrolytic cell? Label the cathodeand anode, and describe the direction of the electronflow.

b. If copper metal is a product of the reaction, is thecell a galvanic cell or electrolytic cell? Label thecathode and anode, and describe the direction of theelectron flow.

c. If the cell is a galvanic cell, determine the standardcell potential.

d. If the cell is electrolytic, determine the minimumexternal potential needed to cause the reactionto occur.

Question:Three electrochemical cells were connected in series so that the same quantity of electrical current passes through all three cells. In the first cell, 1.15 g of chromium metal was deposited from chromium (III) nitrate solution. In the second cell, 3.15 g of osmium was deposited from a solution made of Osn+ and nitrate ions. What is the name of the salt? In the third cell, the electrical charge passed through a solution containing X2+ ions caused deposition of 2.11 g of metallic X. Identify X.

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