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Draw the Lewis structure for HCN. Indicate the hybrid orbitals, and draw a picture showing all the bonds between the atoms labelling each bond as σor π.

Short Answer

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Lewis structure of HCN

HCN contains two σ bonds and two πbonds

Step by step solution

01

About HCN

HCN is a linear molecule that contains one triple bond between a carbon atom and a nitrogen atom, a single bond between a carbon atom and a hydrogen atom. The nitrogen atom contains one free electron pair.

The single bond between hydrogen and carbon represents σas well as one bond between nitrogen and carbon. There are also two πbonds outside the line between two nuclei in between carbon and nitrogen.

02

Lewis structure 

The Lewis structure for HCN is

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Most popular questions from this chapter

The allene molecule has the following Lewis structure:

Must all four hydrogen atoms lie in the same plane? If not, what is the spatial relationship among them? Why?

Complete the Lewis structures of the following molecules. Predict the molecular structure, polarity, bond angles, and hybrid orbitals used by the atoms marked by asterisks for each molecule.

Draw the Lewis structure for .Which of the compounds exhibit at least one bond angle that is approximately 120 degrees? Which of the compounds exhibits hybridization? Which of the compound have a square planar molecular structure? Which of the compounds are polar?

The diatomic molecule OH exist in the gas phase. OH plays an important role in combustion reaction and is a reactive oxidizing agent in polluted air. The bond length and bond energy have been measured to be 97.06 pm and 424.7 kJ/mol, respectively. Assume that the OH molecule is analogous to the HF molecule discussed in the chapter and that the MOs result from the overlap of pz orbital from oxygen and 1s orbital of hydrogen. (The O-H bond lies along the z-axis)

a. Draw a picture of the sigma bonding and antibonding molecular orbitals in OH.

b. Which of the two MOs has the greater hydrogen 1s character?

c. Can the 2px orbital of oxygen form MOs with 1s orbital of hydrogen? Explain.

d. Knowing that only the 2p orbitals of oxygen interact significantly with the 1s orbital of hydrogen, complete the MO diagram for OH. Place the correct number of electrons in the energy level.

e. Estimate the bond order for OH

f. Predict whether the bond order of OH+ is greater than, lesser than, or the same as that of OH+. Explain.

Question: How does molecular orbital theory explain the following observations?

a. H2 is stable, whereas He2 is unstable.

b. B2 and O2 are paramagnetic, whereas C2 , N2and F2 are diamagnetic.

c. N2 has a very large bond energy associated with it.

d. NO+ is more stable than NO- .

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