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The rate constant (k) depends on which of the following? (There may be more than one answer.)

a. the concentration of the reactants

b. the nature of the reactants

c. the temperature

d. the order of the reaction

Explain.

Short Answer

Expert verified

The rate constant depends on the temperature and the order of the given reaction. Hence, options (C) and (D) are correct.

Step by step solution

01

Understanding how the rate constant of reaction depends on the temperature.

The rate of constant over-reaction depends upon the temperature of the reaction.That is rate constant is constant for a particular reaction at a fixed temperature.Increasing the temperature of the reaction generally speeds up the process. That increases the rate because the rate constant increases according to our linear equation.

02

Understanding how great the constant of reaction depends on its order.

The rate constant of a reaction depends upon the order of the reaction. This can be understood by understanding the fact that the sum of the order exponents in the equation determines the unit of the reaction rate constant. We can also see, that for the general reaction, the reaction rate equals the rate constant times the concentration of the reactants each raised to a reaction order.

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Most popular questions from this chapter

Consider the general reaction aA+bBโ†’cCand the following average rate data over a specific time period ฮ”t:

-ฮ”Aฮ”t=0.0080molL-1s-1-ฮ”Bฮ”t=0.0120molL-1s-1-ฮ”Cฮ”t=0.0160molL-1s-1

Determine a set of possible coefficients to balance this general reaction

Many modern refrigerators have an internal temperate of 45โ„‰. What if refrigerators were set at 55โ„‰ in the factory? How would this affect our lives?

Experiments during a recent summer on a number of fireflies (small beetles, Lampyridae photinus) showed that the average interval between flashes of individual insects was 16.3 s at 21.0โฐC and 13.0 s at 27.8โฐC.

  1. What is the apparent activation energy of the reaction that controls the flashing?
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  3. Compare the observed intervals and the one you calculated in part b to the rule of thumb that the Celsius temperature is 54 minus twice the interval between flashes.

A reaction of the form aAโ†’Products,

Gives the plot of ln[A] versus time (in seconds), which is a straight line with a slope of -7.35ร—10-3. Assuming[A]0=0.0100M , calculate the time (in seconds) required for the reaction to reach22.9% completion.

a) Using the free energy profile for a simple one-step reaction, we show that at equilibrium K=kf/kr, where kf and kr are the rate constants for the forward and reverse reactions, respectively. Hint: Use the relationshipโˆ†Gยฐ= -RT In(K), and represent kf and kr using the Arrhenius equation (k = Ae-E2/RT).

b. Why is the following statement false? โ€œA catalyst can increase the rate of a forward reaction but not the rate of the reverse reaction.โ€

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