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A friend of yours states, “A balanced equation tells us how chemicals interact. Therefore, we can determine the rate law directly from the balanced equation.” What do you tell your friend?

Short Answer

Expert verified

The statement is incorrect. In order to able to determine the rate law, we will first have to determine the order for each of the reactants experimentally.

Step by step solution

01

Understanding the meaning of a balanced chemical reaction.

A balanced chemical equation is one for a process in which the overall charge and the number of atoms for each component are the same for both the reactants and the products. In other words, it must be charged a balanced on both sides of the reaction.

02

Understanding the reason why the given statement is incorrect.

The friend’s statement is incorrect.The coefficients only tell us the moles of each of the reactants interacting to form a certain amount of moles of the products. However, in order to determine the rate law for a certain reaction, the order(n) for each of the reactants will have to be determined experimentally since they are not related to the coefficients in the balanced equation.

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Most popular questions from this chapter

Define what is meant by unimolecular and biomolecular steps. Why are termomolecular steps infrequently seen in chemical reactions?

The following data were obtained for the reaction

2ClO2(aq)+2OH-(aq)ClO3-(aq)+ClO2(aq)+H2O(I)

Where,Rate=-d[ClO2]dt

[ClO2]0(mol/L)

role="math" localid="1663766560289" [OH-]0(mol/L)

Initial Rate

(molL-1s-1)

0.0500

0.100

5.75×10-2

0.100

0.100

2.30×10-1

0.100

0.0500

1.15×10-1

a. Determine the rate law and the value of the rate constant.

b. What would be the initial rate for an experiment with[ClO2]0=0.175mol/Land[OH-]0=0.0844mol/L?

One of the concerns about the use of Freons is that theywill migrate to the upper atmosphere, where chlorineAtoms can be generated by the reaction.

CCl2F2⟶CF2Cl + Cl

Freon-12

Chlorine atoms can also act as a catalyst for the destructionof ozone. The activation energy for the reaction

Cl + O3⟶ClO + O2

is 2.1 kJ/mol. Which is the more effective catalyst for thedestruction of ozone, Cl or NO? (See Exercise 94).

The reactionA(aq)+B(aq)Products(aq) was studied, and the following data were obtained:

[A]0(mol/L)

[B]0(mol/L)

InitialRate(molL-1s-1)

0.12

0.18

3.46×10-2

0.060

0.12

1.15×10-2

0.030

0.090

4.32×10-2

0.24

0.090

4.32×10-2

What is the order of the reaction with respect to A?

What is the order of the reaction with respect to B?

What is the value of the rate constant for the reaction?

The ophyl line is a pharmaceutical drug that is sometimes used to help with lung function. You observe a case where the initial lab results indicate that the concentration of the ophyl line in a patient's body decreased from 2.0×10-3M to 1.0×10-3Min 24 hours. In another 12 hours, the drug concentration was found to be5.0×10-4M . What is the value of the rate constant for the metabolism of this drug in the body.

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