Chapter 15: Q4DQ (page 647)
How does temperature affect ‘k’, the rate constant? Explain.
Short Answer
The reaction rate constant depends on the temperature in a way that when the temperature rises, the constant increases as well.
Chapter 15: Q4DQ (page 647)
How does temperature affect ‘k’, the rate constant? Explain.
The reaction rate constant depends on the temperature in a way that when the temperature rises, the constant increases as well.
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Get started for freeThe rate law for the reaction at some temperature is
a. If the half-life for this reaction is 2.00 s when , calculate the value of k for this reaction.
b. How much time is required for the concentration of NOBr to decrease to 0.100 M?
The reaction is believed to occur by the following mechanism:
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Write the rate law for this reaction. Note: Since the reaction is in aqueous solution, the effective concentration of water remains constant. Thus the rate of the forward reaction in the first step can be written as
The following mechanism is proposed for the reduction of by
a. What is the intermediate?
b. Derive an expression for the rate law (rate for the overall reaction using the steady-state approximation.
Write the rate laws of the following elementary reactions.
Question 66: The rate law for the reaction is
The first step in a proposed mechanism is
fast. The second step is rate determining. Write a possible second step for the mechanism.
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