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Question: There is only one value of the equilibrium constant for a particular system at a particular temperature, but there are an infinite number of equilibrium positions. Explain.

Short Answer

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Answer

The infinite number of equilibrium positions is possible for any system at a constant temperature, but all the equilibrium positions have the same equilibrium constant value.

Step by step solution

01

Equilibrium constant

The equilibrium constant for a specific system gives us a definite number at a constant temperature because it is calculated at equilibrium conditions. Therefore, it gives a single number for different initial conditions.

02

Explanation of why there is only one value of the equilibrium constant for a particular system

A specific set of partial pressures/concentrations for the system/reaction that fulfills the equilibrium constant K equation is called an equilibrium position.

There are infinite equilibrium positions for a particular system at a constant temperature. Different partial pressures/concentrations have different equilibrium positions, but these positions have the same K value.

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Most popular questions from this chapter

At a particular temperature, Kp=0.25for the reactionN2O4โ‡Œ2NO2(g)

a. A flask containing only N2O4 at an initial pressure of 4.5 atm is allowed to reach equilibrium. Calculate the equilibrium partial pressures of the gases.

b. A flask containing only NO2 at an initial pressure of 9.0 atm is allowed to reach equilibrium. Calculate the equilibrium partial pressures of the gases.

c. From your answers to parts a and b, does it matter from which direction an equilibrium position is reached?

d. The volume of the container in part a is decreased to one-half the original volume. Calculate the new equilibrium partial pressures.

Question: Explain the difference between K, Kp, and Q.

Methanol, a common laboratory solvent, poses a threat of blindness or death if consumed in sufficient amounts. Once in the body, the substance is oxidized to produce formaldehyde (embalming fluid) and eventually formic acid. Both of these substances are also toxic in varying levels. The equilibrium between methanol and formaldehyde can be described as follows:

CH3OHaqโ‡”H2COaq+H2aq

Assuming the value of K for this reaction is 3.7ร—10-10, what are the equilibrium concentrations of each species if you start with a 1.24 M solution of methanol? What will happen to the concentration of methanol as the formaldehyde is further converted to formic acid?

At 1100 K, for the following reaction:

2SO2(g)+O2(g)โ‡Œ2SO3(g)

Calculate the equilibrium partial pressures of SO2, O2, and SO3 produced from an initial mixture in which PSO2 = PO2 = 0.50 atm and PSO3 = 0.

What will happen to the number of moles of SO3 in equilibrium with and in the reaction

2SO3(g)โ‡Œ2SO2(g)+O2(g)

in each of the following cases?

a. Oxygen gas is added.

b. The pressure is increased by decreasing the volume of the reaction container.

c. In a rigid reaction container, the pressure is increased by adding argon gas.

d. The temperature is decreased (the reaction is endothermic).

e. Gaseous sulfur dioxide is removed.

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