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You make of 1.00La buffered solution by mixing acetic acid and sodium acetate. You have1.00M solutions for each component of the buffered solution. What volume of each solution do you mix to make such a buffered solution?

Short Answer

Expert verified

154mLof sodium acetate and 846mLof acetic acid have to be mixed to make a buffer solution.

Step by step solution

01

Definition of buffer solution

A buffer solution is stated as an aqueous mixture of a weak acid and its corresponding base, or vice versa.

02

Calculations

The molarity of the solution is0.18197.

Molarity=MolesVolumeM1V1VTM2V2VT=0.18197V1=0.18197V2

The total volume of the solutionis1.00L.

V1+V2=1.00L

Now,

0.18197V2+V2=1.001.18197V2=1.00V2=1.001.18197V2=0.846L

V1=1.00-0.846V1=0.154L

Abuffer can be madebymixing154mLof sodium acetate and846mLof acetic acid.

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Most popular questions from this chapter

The following plot shows the pH curves for the titrations of various acids with 0.10 M NaOH (all of the acids were 50.0mL samples of 0.10 M concentration)

  1. Which pH curve corresponds to the weakest acid?
  2. Which pH curve corresponds to the strongest acid?

Which point on the pH curve would you examine to see if this acid is a strong acid or a weak acid (assuming you did not know the initial concentration of the acid)?

c. Which pH curve corresponds to an acid withKa1×10-6?

For the substances in Exercises 97 and 98, which will show increased solubility as the pH of the solution becomes more acidic? Write equations for the reactions that occur to increase the solubility

The solubility of Ce(IO3)3 in a 0.20M KIO3 solution is 4.4 x 10-8 mol/L. Calculate Ksp forCe(IO3)3

a. Calculate the pH of a buffered solution that is 0.100 M in C6H5CO2H (benzoic acid, K = 6.4 X 10-5) and 0.100 M in C6H5CO2Na.
b. Calculate the pH after 20.0% (by moles) of the benzoic acid is converted to benzoate anion by the addition of a strong base. Use the dissociation equilibrium
to calculate the pH.

C6H5CO2H(aq)C6H5CO2-(aq)+H+(aq)
c. Do the same as in part b, but use the following equilibrium to calculate the pH:
C6H5CO2-(aq)+H2O(l)C6H5CO2H(aq)+OH-(aq)
d. Do your answers in parts b and c agree? Explain

Question: What if all you know about two salts is that the value of Ksp for salt A is greater than that of salt B? Why can we not compare the relative solubilities of the salts? Use numbers to show how salt A could be more soluble than salt B, and how salt B can be more soluble than salt A.

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