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Another way to treat data from a pH titration is to graph the absolute value of the change in pH per change in milliliters added versus milliliters added (△pH/△mL versus mL added). Make this graph using your results from Exercise 67. What advantage might this method have over the traditional method for treating titration data?

Short Answer

Expert verified

The advantage of titration graph over traditional plot can be found. On comparing it to the traditional acid base curve of titration, this type is highly accurate to determine the equivalence point.

Step by step solution

01

Data of volume, pH, volume, and pH change 

The table can be drawn as:

Volume

pH

Change in pH

Change in volume

Change in pH/volume

0

2.43

4

3.12

0.69

4

0.1725

8

3.53

0.41

4

0.1025

12.5

3.86

0.33

4.5

0.073333333

20

4.46

0.6

7.5

0.08

24

5.24

0.78

4

0.195

24.5

5.55

0.31

0.5

0.62

24.9

6.26

0.71

0.4

1.775

25

8.13

1.87

0.1

18.7

28

11.75

3.62

3

1.206

30

11.96

0.21

2

0.105

02

Graph of the titration

The graph of the titration can be drawn as:

On comparing it to the traditional acid base curve of titration, this type is highly accurate to determine the equivalence point.

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Most popular questions from this chapter

The solubility of Ce(IO3)3 in a 0.20M KIO3 solution is 4.4 x 10-8 mol/L. Calculate Ksp forCe(IO3)3

Calculate the pH after 0.10 mole of NaOH is added to 1.00 L of the solution in Exercise 27, and calculate the pH after 0.20 mole of HCl is added to 1.00 L of the solution in Exercise 27.

Question:When a diprotic acid H2A2 is titrated with NaOH, the protons on the diprotic acid are generally removed one at a time, resulting in a pH curve that has the following generic shape:


a. Notice that the plot has essentially two titration curves. if the first equivalence point occurs at 100.0 mL NaOH added, what volume of NaOH added corresponds to the second equivalence point?

b. For the following volumes of NaOH added, list the major species present after the OH-reacts completely

i. 0 mL NaOH added

ii. Between 0 and 100.0 mL of NaOH added

iii. 100.0 mL NaOH added

iv. Between 100.0 and 200.0 mL NaOH added

v 200.0 mL NaOH added

vi. After 200.0 mL NAOH added

c. If the pH at 50.0 mL NaOH added is 4.0 and the pH at 150.0 mL NaOH added is 8.0, determine the values Ka1andKa2the diprotic acid.

Calculate the pH of a solution that is 0.40MH2NNH2and0.80MH2NNH3NO3.In order for this buffer to have pH=pKa would you add HClorNaOH?what quantity of which reagent would you add to 1.0Lof the original buffer so that the resulting solution haspH=pKa?

  1. Using theKspfor Cu(OH)2(1.6×10-19)and the overall formation constant for Cu(NH3)4(1.0×1013), calculate a value for the equilibrium constant for the reaction

Cu(OH)2+4NH3(aq)Cu(NH3)42+(aq)+2OH-(aq)

  1. Use the value of the equilibrium constant you calculated in part a to calculate the solubility ofCu(OH)2(s)in 5.0MNH3. In 5.0 M NH3, the concentration of OH-is 0.0095 M.

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