Chapter 14: Carboxylic Acids, Esters, Amines, and Amides

Draw the condensed structural or line-angle formulas for the products from the hydrolysis of each of the following amides with HCl:

a)

b)

c)

d)

e)

Draw the condensed structural or line-angle formulas for the products from the hydrolysis of each of the following amides with $\mathrm{NaOH}$:

a)

b)

c)

d)

e)

a. Identify the functional groups in dicyclanil.

b. The recommended application for dicyclanil for an adult sheep is 65 mg / kg of body mass. If dicyclanil is supplied in a spray with a concentration of 50.mg/mL, how many milliliters of the spray are required to treat a 70.-kg adult sheep?

a. Identify the functional groups in enrofloxacin.

b. The recommended dose for enrofloxacin for sheep is $30.mg/kg$of body mass for $5days$. Enrofloxacin is supplied in $50.-mL$vials with a concentration of $100.mg/mL$. How many vials are needed to treat a $64-kg$sheep for $5days$?

Draw the condensed structural formulas and write the IUPAC names for two structural isomers of the carboxylic acids that have the molecular formula ${\mathrm{C}}_4{\mathrm{H}}_8{\mathrm{O}}_2,(14,1)$

14.5 Draw the condensed structural formulas for $a$and $b$line-angle formulas for $c$and $d$:

a. $3,4$-dibromobutanoic acid

b. $2$-chloropropanoic acid

c. benzoic acid

d. heptanoic acid

Draw the condensed structural formulas and write the IUPAC names for four structural isomers of the esters that have the molecular formula ${\mathrm{C}}_3{\mathrm{H}}_1{\mathrm{O}}_2·(14.3)$

The ester methyl butanoate has the odor and flavor of strawberries. $(14.3,14.4)$

a. Draw the condensed structural formula for methyl butanoate.

b. Write the IUPAC name for the carboxylic acid and the alcohol used to prepare methyl butanoate.

c. Write the balanced chemical equation for the acid hydrolysis of methyl butanoate.

Methyl benzoate, which smells like pineapple guava, is used to train detection dogs. (14.3, 14.4)

a. Draw the line-angle formula for methyl benzoate.

b. Write the IUPAC name for the carboxylic acid and alcohol used to prepare methyl benzoate.

c. Write the balanced chemical equation for the acid hydrolysis of methyl benzoate.

Phenylephrine is the active ingredient in some nose sprays used to reduce swelling of nasal membranes.

Identify the functional groups in phenylephrine. $(14.1,14.3,14.5,14.6)$