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Problem 37

The general formula of an ionic compound crystallizing in zinc blende structure is (a) \(\mathrm{AB}_{3}\) (b) \(\mathrm{AB}_{2}\) (c) \(\mathrm{A}_{2} \mathrm{~B}_{2}\) (d) \(\mathrm{AB}\)

Problem 38

Which of the following statements is not correct? (a) The density of the crystal exhibiting Frenkel defect is less as compared to that of the perfect crystal (b) The Schottky defects are more common in ionic compounds with high coordination numbers and where the sizes of ions are small (c) In alkali halides, Frenkel defects are not found (d) The density of the crystal exhibiting Schottky defect is less as compared to that of the perfect crystal

Problem 39

Which of the following statements is not correct? (a) Heating of zinc oxide leads to the formation of a yellow coloured non- stoichiometric compound (b) The creation of cationic holes in ionic crystals imparts electrical conductivity to such crystals (c) The compound ferrous oxide can be prepared in its stoichiometric composition (d) Silver bromide shows both types of Schottky and Frenkel defects

Problem 40

On heating some polar crystals, weak electric current is produced. It is termed as (a) superconductivity (b) piezoelectricity (c) photoelectric current (d) none of these

Problem 41

Mark the correct statement (a) CsCl crystal show Schottky defect (b) Crystals having F-centres are coloured and paramagnetic (c) Photo sensitivity of AgBr is due to the presence of Frenkel defect in its crystals (d) all of these are correct

Problem 42

Which substance will conduct electric current in the solid state? (a) Diamond (b) Graphite (c) Sodium chloride (d) Iodine

Problem 43

The substance which possesses zero resistance at \(0 \mathrm{~K}\) is called (a) Super conductor (b) Insulator (c) Conductor (d) Semiconductor

Problem 44

In which of the following structures, the cation has maximum coordination number? (a) \(\mathrm{NaCl}\) (b) \(\mathrm{Na}_{2} \mathrm{O}\) (c) zinc blende (d) \(\mathrm{CaF}_{2}\)

Problem 45

In the zinc blende structure \((\mathrm{ZnS}), \mathrm{S}^{2}\) adopt ccp arrangement and \(\mathrm{Zn}^{2+}\) occupy (a) Alternate tetrahedral sites (b) Octahedral sites (c) Tetrahedral sites (d) Both octahedral and tetrahedral sites

Problem 46

An example of ferroelectric substance is (a) Tourmaline (b) Quartz (c) Barium titanate (d) Lead zirconate

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